Kinetics and mechanism of in situ simultaneous formation of metal nanoparticles in stabilizing polymer matrix

Anatolii D. Pomogailo; Gulzhian I. Dzhardimalieva; Aleksander S. Rozenberg; Dmitri N. Muraviev

doi:10.1023/B:NANO.0000006091.92638.a5

Kinetics and mechanism of in situ simultaneous formation of metal nanoparticles in stabilizing polymer matrix

Anatolii D. Pomogailo, Gulzhian I. Dzhardimalieva, Aleksander S. Rozenberg, Dmitri N. Muraviev

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

52 Citations (Scopus)

Abstract

The kinetic peculiarities of the thermal transformations of unsaturated metal carboxylates (transition metal acrylates and maleates as well as their cocrystallites) and properties of metal-polymer nanocomposites formed have been studied. The composition and structure of metal-containing precursors and the products of the thermolysis were identified by X-ray analysis, optical and electron microscopy, magnetic measurements, EXAFS, IR and mass spectroscopy. The thermal transformations of metal-containing monomers studied are the complex process including dehydration, solid phase polymerization, and thermolysis process which proceed at varied temperature ranges. At 200-300°C the rate of thermal decay can be described by first-order equations. The products of decompositions are nanometer-sized particles of metal or its oxides with a narrow size distribution (the mean particle diameter of 5-10 nm) stabilized by the polymer matrix.

Original language	English
Pages (from-to)	497-519
Journal	Journal of Nanoparticle Research
Volume	5
Issue number	5-6
DOIs	https://doi.org/10.1023/B:NANO.0000006091.92638.a5
Publication status	Published - 1 Dec 2003

Keywords

Decarboxylation
Dehydration
Mechanism
Metal carboxylates
Metal nanoparticles
Molecular structure
Nanocomposites
Polymer matrix
Polymerization
Thermolysis

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title = "Kinetics and mechanism of in situ simultaneous formation of metal nanoparticles in stabilizing polymer matrix",

abstract = "The kinetic peculiarities of the thermal transformations of unsaturated metal carboxylates (transition metal acrylates and maleates as well as their cocrystallites) and properties of metal-polymer nanocomposites formed have been studied. The composition and structure of metal-containing precursors and the products of the thermolysis were identified by X-ray analysis, optical and electron microscopy, magnetic measurements, EXAFS, IR and mass spectroscopy. The thermal transformations of metal-containing monomers studied are the complex process including dehydration, solid phase polymerization, and thermolysis process which proceed at varied temperature ranges. At 200-300°C the rate of thermal decay can be described by first-order equations. The products of decompositions are nanometer-sized particles of metal or its oxides with a narrow size distribution (the mean particle diameter of 5-10 nm) stabilized by the polymer matrix.",

keywords = "Decarboxylation, Dehydration, Mechanism, Metal carboxylates, Metal nanoparticles, Molecular structure, Nanocomposites, Polymer matrix, Polymerization, Thermolysis",

author = "Pomogailo, {Anatolii D.} and Dzhardimalieva, {Gulzhian I.} and Rozenberg, {Aleksander S.} and Muraviev, {Dmitri N.}",

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Kinetics and mechanism of in situ simultaneous formation of metal nanoparticles in stabilizing polymer matrix. / Pomogailo, Anatolii D.; Dzhardimalieva, Gulzhian I.; Rozenberg, Aleksander S.; Muraviev, Dmitri N.

In: Journal of Nanoparticle Research, Vol. 5, No. 5-6, 01.12.2003, p. 497-519.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Kinetics and mechanism of in situ simultaneous formation of metal nanoparticles in stabilizing polymer matrix

AU - Pomogailo, Anatolii D.

AU - Dzhardimalieva, Gulzhian I.

AU - Rozenberg, Aleksander S.

AU - Muraviev, Dmitri N.

PY - 2003/12/1

Y1 - 2003/12/1

N2 - The kinetic peculiarities of the thermal transformations of unsaturated metal carboxylates (transition metal acrylates and maleates as well as their cocrystallites) and properties of metal-polymer nanocomposites formed have been studied. The composition and structure of metal-containing precursors and the products of the thermolysis were identified by X-ray analysis, optical and electron microscopy, magnetic measurements, EXAFS, IR and mass spectroscopy. The thermal transformations of metal-containing monomers studied are the complex process including dehydration, solid phase polymerization, and thermolysis process which proceed at varied temperature ranges. At 200-300°C the rate of thermal decay can be described by first-order equations. The products of decompositions are nanometer-sized particles of metal or its oxides with a narrow size distribution (the mean particle diameter of 5-10 nm) stabilized by the polymer matrix.

AB - The kinetic peculiarities of the thermal transformations of unsaturated metal carboxylates (transition metal acrylates and maleates as well as their cocrystallites) and properties of metal-polymer nanocomposites formed have been studied. The composition and structure of metal-containing precursors and the products of the thermolysis were identified by X-ray analysis, optical and electron microscopy, magnetic measurements, EXAFS, IR and mass spectroscopy. The thermal transformations of metal-containing monomers studied are the complex process including dehydration, solid phase polymerization, and thermolysis process which proceed at varied temperature ranges. At 200-300°C the rate of thermal decay can be described by first-order equations. The products of decompositions are nanometer-sized particles of metal or its oxides with a narrow size distribution (the mean particle diameter of 5-10 nm) stabilized by the polymer matrix.

KW - Decarboxylation

KW - Dehydration

KW - Mechanism

KW - Metal carboxylates

KW - Metal nanoparticles

KW - Molecular structure

KW - Nanocomposites

KW - Polymer matrix

KW - Polymerization

KW - Thermolysis

U2 - 10.1023/B:NANO.0000006091.92638.a5

DO - 10.1023/B:NANO.0000006091.92638.a5

M3 - Article

VL - 5

SP - 497

EP - 519

JO - Journal of Nanoparticle Research

JF - Journal of Nanoparticle Research

SN - 1388-0764

IS - 5-6

ER -