Isostructuralism in double complex salts series: [M(H2O)x(NH3)6-x] [M′(CN)6] and [M(H2O)x(NH3)6-x] [CuCl5] (M, M′ = Co(III), Cr(III); x = 0, 1, 2). Crystal structure of [Cr(H2O)(NH3)5] [CuCl5]

J. Pons; A. Solans; J. C. Bayon; E. Molins; J. Casabo; F. Palacio; F. Plana

doi:10.1016/S0020-1693(00)82040-X

Isostructuralism in double complex salts series: [M(H₂O)_x(NH₃)_6-x] [M′(CN)₆] and [M(H₂O)_x(NH₃)_6-x] [CuCl₅] (M, M′ = Co(III), Cr(III); x = 0, 1, 2). Crystal structure of [Cr(H₂O)(NH₃)₅] [CuCl₅]

J. Pons, A. Solans, J. C. Bayon, E. Molins, J. Casabo, F. Palacio, F. Plana

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

5 Citations (Scopus)

Abstract

Isostructuralism in two series of double complex salts [M(H2O)x(NH3)6-x] [M′(CN)6] (M, M′= Co(III), Cr(III); x = 0, 1, 2) and [M(H2O)x- (NH3)6-x] [CuCl5] (M = Co(III), Cr(III); x = 0, 1, 2) is reported by the use of X-ray powder diffraction methods. Compounds from the first series belong to the space group R 3, while those from the second belong to the Fd3c group. The crystal structure of [Cr(H2O)(NH3)5] [CuCl5], solved by single crystal X-ray diffraction methods, is cubic, space group Fd3c, with a = 22.208(3) Å, V = 10952 Å3, Z = 32, Dx = 1.92 g cm-1, μ = 9.57 cm-1, F(000) = 6336, Mw = 395.98. Disorder of the water molecule of the [Cr(H2O)(NH3)5]3+ cation among the six coordination sites of the octahedrally coordinated Cr(III) ion was found. A possible explanation of the isomorphism between the compounds within each series is proposed. © 1990.

Original language	English
Pages (from-to)	91-95
Journal	Inorganica Chimica Acta
Volume	169
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)82040-X
Publication status	Published - 1 Mar 1990

Access to Document

10.1016/S0020-1693(00)82040-X

Fingerprint Dive into the research topics of 'Isostructuralism in double complex salts series: [M(H2O)x(NH3)6-x] [M′(CN)6] and [M(H2O)x(NH3)6-x] [CuCl5] (M, M′ = Co(III), Cr(III); x = 0, 1, 2). Crystal structure of [Cr(H2O)(NH3)5] [CuCl5]'. Together they form a unique fingerprint.

Cite this

Pons, J., Solans, A., Bayon, J. C., Molins, E., Casabo, J., Palacio, F., & Plana, F. (1990). Isostructuralism in double complex salts series: [M(H₂O)_x(NH₃)_6-x] [M′(CN)₆] and [M(H₂O)_x(NH₃)_6-x] [CuCl₅] (M, M′ = Co(III), Cr(III); x = 0, 1, 2). Crystal structure of [Cr(H₂O)(NH₃)₅] [CuCl₅]. Inorganica Chimica Acta, 169(1), 91-95. https://doi.org/10.1016/S0020-1693(00)82040-X

@article{ffb6fa66d727413daf324f3cdb971275,

title = "Isostructuralism in double complex salts series: [M(H2O)x(NH3)6-x] [M′(CN)6] and [M(H2O)x(NH3)6-x] [CuCl5] (M, M′ = Co(III), Cr(III); x = 0, 1, 2). Crystal structure of [Cr(H2O)(NH3)5] [CuCl5]",

abstract = "Isostructuralism in two series of double complex salts [M(H2O)x(NH3)6-x] [M′(CN)6] (M, M′= Co(III), Cr(III); x = 0, 1, 2) and [M(H2O)x- (NH3)6-x] [CuCl5] (M = Co(III), Cr(III); x = 0, 1, 2) is reported by the use of X-ray powder diffraction methods. Compounds from the first series belong to the space group R 3, while those from the second belong to the Fd3c group. The crystal structure of [Cr(H2O)(NH3)5] [CuCl5], solved by single crystal X-ray diffraction methods, is cubic, space group Fd3c, with a = 22.208(3) {\AA}, V = 10952 {\AA}3, Z = 32, Dx = 1.92 g cm-1, μ = 9.57 cm-1, F(000) = 6336, Mw = 395.98. Disorder of the water molecule of the [Cr(H2O)(NH3)5]3+ cation among the six coordination sites of the octahedrally coordinated Cr(III) ion was found. A possible explanation of the isomorphism between the compounds within each series is proposed. {\textcopyright} 1990.",

author = "J. Pons and A. Solans and Bayon, {J. C.} and E. Molins and J. Casabo and F. Palacio and F. Plana",

year = "1990",

month = mar,

day = "1",

doi = "10.1016/S0020-1693(00)82040-X",

language = "English",

volume = "169",

pages = "91--95",

number = "1",

}

Pons, J, Solans, A, Bayon, JC, Molins, E, Casabo, J, Palacio, F & Plana, F 1990, 'Isostructuralism in double complex salts series: [M(H₂O)_x(NH₃)_6-x] [M′(CN)₆] and [M(H₂O)_x(NH₃)_6-x] [CuCl₅] (M, M′ = Co(III), Cr(III); x = 0, 1, 2). Crystal structure of [Cr(H₂O)(NH₃)₅] [CuCl₅]', Inorganica Chimica Acta, vol. 169, no. 1, pp. 91-95. https://doi.org/10.1016/S0020-1693(00)82040-X

Isostructuralism in double complex salts series: [M(H₂O)_x(NH₃)_6-x] [M′(CN)₆] and [M(H₂O)_x(NH₃)_6-x] [CuCl₅] (M, M′ = Co(III), Cr(III); x = 0, 1, 2). Crystal structure of [Cr(H₂O)(NH₃)₅] [CuCl₅]. / Pons, J.; Solans, A.; Bayon, J. C.; Molins, E.; Casabo, J.; Palacio, F.; Plana, F.

In: Inorganica Chimica Acta, Vol. 169, No. 1, 01.03.1990, p. 91-95.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Isostructuralism in double complex salts series: [M(H2O)x(NH3)6-x] [M′(CN)6] and [M(H2O)x(NH3)6-x] [CuCl5] (M, M′ = Co(III), Cr(III); x = 0, 1, 2). Crystal structure of [Cr(H2O)(NH3)5] [CuCl5]

AU - Pons, J.

AU - Solans, A.

AU - Bayon, J. C.

AU - Molins, E.

AU - Casabo, J.

AU - Palacio, F.

AU - Plana, F.

PY - 1990/3/1

Y1 - 1990/3/1

N2 - Isostructuralism in two series of double complex salts [M(H2O)x(NH3)6-x] [M′(CN)6] (M, M′= Co(III), Cr(III); x = 0, 1, 2) and [M(H2O)x- (NH3)6-x] [CuCl5] (M = Co(III), Cr(III); x = 0, 1, 2) is reported by the use of X-ray powder diffraction methods. Compounds from the first series belong to the space group R 3, while those from the second belong to the Fd3c group. The crystal structure of [Cr(H2O)(NH3)5] [CuCl5], solved by single crystal X-ray diffraction methods, is cubic, space group Fd3c, with a = 22.208(3) Å, V = 10952 Å3, Z = 32, Dx = 1.92 g cm-1, μ = 9.57 cm-1, F(000) = 6336, Mw = 395.98. Disorder of the water molecule of the [Cr(H2O)(NH3)5]3+ cation among the six coordination sites of the octahedrally coordinated Cr(III) ion was found. A possible explanation of the isomorphism between the compounds within each series is proposed. © 1990.

AB - Isostructuralism in two series of double complex salts [M(H2O)x(NH3)6-x] [M′(CN)6] (M, M′= Co(III), Cr(III); x = 0, 1, 2) and [M(H2O)x- (NH3)6-x] [CuCl5] (M = Co(III), Cr(III); x = 0, 1, 2) is reported by the use of X-ray powder diffraction methods. Compounds from the first series belong to the space group R 3, while those from the second belong to the Fd3c group. The crystal structure of [Cr(H2O)(NH3)5] [CuCl5], solved by single crystal X-ray diffraction methods, is cubic, space group Fd3c, with a = 22.208(3) Å, V = 10952 Å3, Z = 32, Dx = 1.92 g cm-1, μ = 9.57 cm-1, F(000) = 6336, Mw = 395.98. Disorder of the water molecule of the [Cr(H2O)(NH3)5]3+ cation among the six coordination sites of the octahedrally coordinated Cr(III) ion was found. A possible explanation of the isomorphism between the compounds within each series is proposed. © 1990.

U2 - 10.1016/S0020-1693(00)82040-X

DO - 10.1016/S0020-1693(00)82040-X

M3 - Article

VL - 169

SP - 91

EP - 95

IS - 1

ER -