Intramolecular σ-bond metathesis/protonolysis on zirconium(IV) and hafnium(IV) pyridylamido olefin polymerization catalyst precursors: Exploring unexpected reactivity paths

Lapo Luconi, Giuliano Giambastiani, Andrea Rossin, Claudio Bianchini, Agustí Lledós

Research output: Contribution to journalArticleResearchpeer-review

14 Citations (Scopus)

Abstract

A temperature-controlled metathesis/protonolysis takes place on group 4 amidopyridinate polymerization catalyst precursors. Unraveling this unprecedented reactivity path allowed us to highlight the importance of the metal precursor choice while preparing improved catalytic structures or studying new catalytic processes. © 2010 American Chemical Society.
Original languageEnglish
Pages (from-to)6811-6813
JournalInorganic Chemistry
Volume49
Issue number15
DOIs
Publication statusPublished - 2 Aug 2010

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