Intramolecular σ-bond metathesis/protonolysis on zirconium(IV) and hafnium(IV) pyridylamido olefin polymerization catalyst precursors: Exploring unexpected reactivity paths

Lapo Luconi; Giuliano Giambastiani; Andrea Rossin; Claudio Bianchini; Agustí Lledós

doi:10.1021/ic100947q

Intramolecular σ-bond metathesis/protonolysis on zirconium(IV) and hafnium(IV) pyridylamido olefin polymerization catalyst precursors: Exploring unexpected reactivity paths

Lapo Luconi, Giuliano Giambastiani, Andrea Rossin, Claudio Bianchini, Agustí Lledós

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

14 Citations (Scopus)

Abstract

A temperature-controlled metathesis/protonolysis takes place on group 4 amidopyridinate polymerization catalyst precursors. Unraveling this unprecedented reactivity path allowed us to highlight the importance of the metal precursor choice while preparing improved catalytic structures or studying new catalytic processes. © 2010 American Chemical Society.

Original language	English
Pages (from-to)	6811-6813
Journal	Inorganic Chemistry
Volume	49
Issue number	15
DOIs	https://doi.org/10.1021/ic100947q
Publication status	Published - 2 Aug 2010

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10.1021/ic100947q

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Luconi, L., Giambastiani, G., Rossin, A., Bianchini, C., & Lledós, A. (2010). Intramolecular σ-bond metathesis/protonolysis on zirconium(IV) and hafnium(IV) pyridylamido olefin polymerization catalyst precursors: Exploring unexpected reactivity paths. Inorganic Chemistry, 49(15), 6811-6813. https://doi.org/10.1021/ic100947q

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abstract = "A temperature-controlled metathesis/protonolysis takes place on group 4 amidopyridinate polymerization catalyst precursors. Unraveling this unprecedented reactivity path allowed us to highlight the importance of the metal precursor choice while preparing improved catalytic structures or studying new catalytic processes. {\textcopyright} 2010 American Chemical Society.",

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Intramolecular σ-bond metathesis/protonolysis on zirconium(IV) and hafnium(IV) pyridylamido olefin polymerization catalyst precursors: Exploring unexpected reactivity paths. / Luconi, Lapo; Giambastiani, Giuliano; Rossin, Andrea; Bianchini, Claudio; Lledós, Agustí.

In: Inorganic Chemistry, Vol. 49, No. 15, 02.08.2010, p. 6811-6813.

Research output: Contribution to journal › Article › Research › peer-review

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AU - Lledós, Agustí

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