Insertion of Carbon Disulfide into Ruthenium—Alkenyl Bonds. Formation of an Alkenedithiocarboxylate Ligand

M. Rosario Torres; Aurea Peraies; Josep Ros

doi:10.1021/om00095a033

Insertion of Carbon Disulfide into Ruthenium—Alkenyl Bonds. Formation of an Alkenedithiocarboxylate Ligand

M. Rosario Torres, Aurea Peraies, Josep Ros

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

31 Citations (Scopus)

Abstract

CS2reacts with complexes Ru(CO)Cl(HC= CHR)(PPh3)2(R=Ph or t-Bu) to give products Ru(CO)-Cl(S2C(H)C=CHR)(PPh3)2(R = Ph (1) and t-Bu (2)). The Insertion products contain an alkenedithiocarboxylate ligand coordinated through two sulfur atoms. The structure of 1 has been established by an X-ray diffraction study. © 1988, American Chemical Society. All rights reserved.

Original language	English
Pages (from-to)	1223-1224
Journal	Organometallics
Volume	7
Issue number	5
DOIs	https://doi.org/10.1021/om00095a033
Publication status	Published - 1 Jan 1988

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title = "Insertion of Carbon Disulfide into Ruthenium—Alkenyl Bonds. Formation of an Alkenedithiocarboxylate Ligand",

abstract = "CS2reacts with complexes Ru(CO)Cl(HC= CHR)(PPh3)2(R=Ph or t-Bu) to give products Ru(CO)-Cl(S2C(H)C=CHR)(PPh3)2(R = Ph (1) and t-Bu (2)). The Insertion products contain an alkenedithiocarboxylate ligand coordinated through two sulfur atoms. The structure of 1 has been established by an X-ray diffraction study. {\textcopyright} 1988, American Chemical Society. All rights reserved.",

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T1 - Insertion of Carbon Disulfide into Ruthenium—Alkenyl Bonds. Formation of an Alkenedithiocarboxylate Ligand

AU - Torres, M. Rosario

AU - Peraies, Aurea

AU - Ros, Josep

PY - 1988/1/1

Y1 - 1988/1/1

N2 - CS2reacts with complexes Ru(CO)Cl(HC= CHR)(PPh3)2(R=Ph or t-Bu) to give products Ru(CO)-Cl(S2C(H)C=CHR)(PPh3)2(R = Ph (1) and t-Bu (2)). The Insertion products contain an alkenedithiocarboxylate ligand coordinated through two sulfur atoms. The structure of 1 has been established by an X-ray diffraction study. © 1988, American Chemical Society. All rights reserved.

AB - CS2reacts with complexes Ru(CO)Cl(HC= CHR)(PPh3)2(R=Ph or t-Bu) to give products Ru(CO)-Cl(S2C(H)C=CHR)(PPh3)2(R = Ph (1) and t-Bu (2)). The Insertion products contain an alkenedithiocarboxylate ligand coordinated through two sulfur atoms. The structure of 1 has been established by an X-ray diffraction study. © 1988, American Chemical Society. All rights reserved.

U2 - 10.1021/om00095a033

DO - 10.1021/om00095a033

M3 - Article

VL - 7

SP - 1223

EP - 1224

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 5

ER -