Insertion of a water oxygen atom into a phosphorus-metal bond: From a P-coordinated (diphenylphosphino)alkyne to a coordinated η2(O,C)-vinyldiphenylphosphine oxide

Elmostafa Louattani; Isabel Moldes; Joan Suades; Joan F. Piniella; Angel Alvarez-Larena

Insertion of a water oxygen atom into a phosphorus-metal bond: From a P-coordinated (diphenylphosphino)alkyne to a coordinated η²(O,C)-vinyldiphenylphosphine oxide

Elmostafa Louattani, Isabel Moldes, Joan Suades, Joan F. Piniella, Angel Alvarez-Larena

Research output: Contribution to journal › Article › Research › peer-review

Abstract

The reaction of [(Fp)Ph2PC≡CR][BF4] (Fp = (C5H5)Fe(CO)2; R = H (1), Me (2), tBu (3), Ph (4), Tol (5)) with (CH3)3NO·2H2O (6) was studied, and the new complexes [CpFe(CO)(η2(O,C)-Ph2P(O)CH=CR)] (R = Ph (7), Tol (8)) were isolated. Compound 8 was characterized by X-ray diffraction. An isotopic labeling study showed that the oxygen atom bonded to phosphorus came from a water molecule.

Original language	English
Pages (from-to)	3394-3397
Journal	Organometallics
Volume	17
Issue number	15
Publication status	Published - 20 Jul 1998

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@article{fe89cfdc027a4bd0b7dfc3d7d40f1219,

title = "Insertion of a water oxygen atom into a phosphorus-metal bond: From a P-coordinated (diphenylphosphino)alkyne to a coordinated η2(O,C)-vinyldiphenylphosphine oxide",

abstract = "The reaction of [(Fp)Ph2PC≡CR][BF4] (Fp = (C5H5)Fe(CO)2; R = H (1), Me (2), tBu (3), Ph (4), Tol (5)) with (CH3)3NO·2H2O (6) was studied, and the new complexes [CpFe(CO)(η2(O,C)-Ph2P(O)CH=CR)] (R = Ph (7), Tol (8)) were isolated. Compound 8 was characterized by X-ray diffraction. An isotopic labeling study showed that the oxygen atom bonded to phosphorus came from a water molecule.",

author = "Elmostafa Louattani and Isabel Moldes and Joan Suades and Piniella, {Joan F.} and Angel Alvarez-Larena",

year = "1998",

month = jul,

day = "20",

language = "English",

volume = "17",

pages = "3394--3397",

journal = "Organometallics",

issn = "0276-7333",

number = "15",

}

Insertion of a water oxygen atom into a phosphorus-metal bond: From a P-coordinated (diphenylphosphino)alkyne to a coordinated η²(O,C)-vinyldiphenylphosphine oxide. / Louattani, Elmostafa; Moldes, Isabel; Suades, Joan; Piniella, Joan F.; Alvarez-Larena, Angel.

In: Organometallics, Vol. 17, No. 15, 20.07.1998, p. 3394-3397.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Insertion of a water oxygen atom into a phosphorus-metal bond: From a P-coordinated (diphenylphosphino)alkyne to a coordinated η2(O,C)-vinyldiphenylphosphine oxide

AU - Louattani, Elmostafa

AU - Moldes, Isabel

AU - Suades, Joan

AU - Piniella, Joan F.

AU - Alvarez-Larena, Angel

PY - 1998/7/20

Y1 - 1998/7/20

N2 - The reaction of [(Fp)Ph2PC≡CR][BF4] (Fp = (C5H5)Fe(CO)2; R = H (1), Me (2), tBu (3), Ph (4), Tol (5)) with (CH3)3NO·2H2O (6) was studied, and the new complexes [CpFe(CO)(η2(O,C)-Ph2P(O)CH=CR)] (R = Ph (7), Tol (8)) were isolated. Compound 8 was characterized by X-ray diffraction. An isotopic labeling study showed that the oxygen atom bonded to phosphorus came from a water molecule.

AB - The reaction of [(Fp)Ph2PC≡CR][BF4] (Fp = (C5H5)Fe(CO)2; R = H (1), Me (2), tBu (3), Ph (4), Tol (5)) with (CH3)3NO·2H2O (6) was studied, and the new complexes [CpFe(CO)(η2(O,C)-Ph2P(O)CH=CR)] (R = Ph (7), Tol (8)) were isolated. Compound 8 was characterized by X-ray diffraction. An isotopic labeling study showed that the oxygen atom bonded to phosphorus came from a water molecule.

M3 - Article

VL - 17

SP - 3394

EP - 3397

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 15

ER -