Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives

Michel Weïwer, Xavier Chaminade, J. Carles Bayón, Elisabet Duñach

Research output: Contribution to journalArticleResearchpeer-review

32 Citations (Scopus)

Abstract

InIII triflate-catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
Original languageEnglish
Pages (from-to)2464-2469
JournalEuropean Journal of Organic Chemistry
Issue number15
DOIs
Publication statusPublished - 25 Jun 2007

Keywords

  • Camphene
  • Hydrothiolation
  • Indium triflate
  • Rearrangement
  • Thioacetylation

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