Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives

Michel Weïwer; Xavier Chaminade; J. Carles Bayón; Elisabet Duñach

doi:10.1002/ejoc.200601112

Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives

Michel Weïwer, Xavier Chaminade, J. Carles Bayón, Elisabet Duñach

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

37 Citations (Scopus)

Abstract

InIII triflate-catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

Original language	English
Pages (from-to)	2464-2469
Journal	European Journal of Organic Chemistry
Issue number	15
DOIs	https://doi.org/10.1002/ejoc.200601112 https://doi.org/10.1002/chin.200736053
Publication status	Published - 25 Jun 2007

Keywords

Camphene
Hydrothiolation
Indium triflate
Rearrangement
Thioacetylation

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title = "Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives",

abstract = "InIII triflate-catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. {\textcopyright} Wiley-VCH Verlag GmbH & Co. KGaA, 2007.",

keywords = "Camphene, Hydrothiolation, Indium triflate, Rearrangement, Thioacetylation",

author = "Michel We{\"i}wer and Xavier Chaminade and Bay{\'o}n, {J. Carles} and Elisabet Du{\~n}ach",

year = "2007",

month = jun,

day = "25",

doi = "10.1002/ejoc.200601112",

language = "English",

pages = "2464--2469",

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TY - JOUR

T1 - Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives

AU - Weïwer, Michel

AU - Chaminade, Xavier

AU - Bayón, J. Carles

AU - Duñach, Elisabet

PY - 2007/6/25

Y1 - 2007/6/25

N2 - InIII triflate-catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

AB - InIII triflate-catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

KW - Camphene

KW - Hydrothiolation

KW - Indium triflate

KW - Rearrangement

KW - Thioacetylation

U2 - 10.1002/ejoc.200601112

DO - 10.1002/ejoc.200601112

M3 - Article

SN - 1434-193X

SP - 2464

EP - 2469

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 15

ER -

Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives

Abstract

Keywords

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