Implementing multiplicity editing in selective HSQMBC experiments

Josep Saurí; Eduard Sistaré; R. Thomas Williamson; Gary E. Martin; Teodor Parella

doi:10.1016/j.jmr.2015.01.006

Implementing multiplicity editing in selective HSQMBC experiments

Josep Saurí, Eduard Sistaré, R. Thomas Williamson, Gary E. Martin, Teodor Parella

Research output: Contribution to journal › Article › Research › peer-review

9 Citations (Scopus)

Abstract

© 2015 Elsevier Inc. All rights reserved. Even C/CH2 and odd CH/CH3 carbon-multiplicity information can be directly distinguished from the relative positive/negative phase of cross-peaks in a novel ME (Multiplicity-Edited)-selHSQMBC experiment. The method can be extended by a TOCSY propagation step, and it is fully compatible for the simultaneous and precise determination of long-range heteronuclear coupling constants. Broadband homonuclear decoupling techniques can also be incorporated to enhance sensitivity and signal resolution by effective collapse of J(HH) multiplets.

Original language	English
Pages (from-to)	170-175
Journal	Journal of Magnetic Resonance
Volume	252
DOIs	https://doi.org/10.1016/j.jmr.2015.01.006
Publication status	Published - 1 Jan 2015

Keywords

Heteronuclear coupling constants
HOBS
HSQMBC
IPAP
Multiplicity-editing

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10.1016/j.jmr.2015.01.006

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title = "Implementing multiplicity editing in selective HSQMBC experiments",

abstract = "{\textcopyright} 2015 Elsevier Inc. All rights reserved. Even C/CH2 and odd CH/CH3 carbon-multiplicity information can be directly distinguished from the relative positive/negative phase of cross-peaks in a novel ME (Multiplicity-Edited)-selHSQMBC experiment. The method can be extended by a TOCSY propagation step, and it is fully compatible for the simultaneous and precise determination of long-range heteronuclear coupling constants. Broadband homonuclear decoupling techniques can also be incorporated to enhance sensitivity and signal resolution by effective collapse of J(HH) multiplets.",

keywords = "Heteronuclear coupling constants, HOBS, HSQMBC, IPAP, Multiplicity-editing",

author = "Josep Saur{\'i} and Eduard Sistar{\'e} and {Thomas Williamson}, R. and Martin, {Gary E.} and Teodor Parella",

year = "2015",

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doi = "10.1016/j.jmr.2015.01.006",

language = "English",

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TY - JOUR

T1 - Implementing multiplicity editing in selective HSQMBC experiments

AU - Saurí, Josep

AU - Sistaré, Eduard

AU - Thomas Williamson, R.

AU - Martin, Gary E.

AU - Parella, Teodor

PY - 2015/1/1

Y1 - 2015/1/1

N2 - © 2015 Elsevier Inc. All rights reserved. Even C/CH2 and odd CH/CH3 carbon-multiplicity information can be directly distinguished from the relative positive/negative phase of cross-peaks in a novel ME (Multiplicity-Edited)-selHSQMBC experiment. The method can be extended by a TOCSY propagation step, and it is fully compatible for the simultaneous and precise determination of long-range heteronuclear coupling constants. Broadband homonuclear decoupling techniques can also be incorporated to enhance sensitivity and signal resolution by effective collapse of J(HH) multiplets.

AB - © 2015 Elsevier Inc. All rights reserved. Even C/CH2 and odd CH/CH3 carbon-multiplicity information can be directly distinguished from the relative positive/negative phase of cross-peaks in a novel ME (Multiplicity-Edited)-selHSQMBC experiment. The method can be extended by a TOCSY propagation step, and it is fully compatible for the simultaneous and precise determination of long-range heteronuclear coupling constants. Broadband homonuclear decoupling techniques can also be incorporated to enhance sensitivity and signal resolution by effective collapse of J(HH) multiplets.

KW - Heteronuclear coupling constants

KW - HOBS

KW - HSQMBC

KW - IPAP

KW - Multiplicity-editing

U2 - 10.1016/j.jmr.2015.01.006

DO - 10.1016/j.jmr.2015.01.006

M3 - Article

VL - 252

SP - 170

EP - 175

ER -

Implementing multiplicity editing in selective HSQMBC experiments

Abstract

Keywords

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