Hybrid organic-inorganic materials from di-(2-pyridyl)methylamine-palladium dichloride complex as recoverable catalysts for Suzuki, Heck and Sonogashira reactions

Montserrat Trilla; Roser Pleixats; Michel Wong Chi Man; Catherine Bied; Joël J.E. Moreau

doi:10.1002/adsc.200700489

Hybrid organic-inorganic materials from di-(2-pyridyl)methylamine-palladium dichloride complex as recoverable catalysts for Suzuki, Heck and Sonogashira reactions

Montserrat Trilla, Roser Pleixats, Michel Wong Chi Man, Catherine Bied, Joël J.E. Moreau

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

76 Citations (Scopus)

Abstract

Hybrid silica materials containing the di-(2-pyridyl)methylamine-palladium dichloride complex, prepared by sol-gel cogelification, are efficient recyclable catalysts for Suzuki (aryl bromides and chlorides), Heck (aryl bromides) and Sonogashira reactions (aryl iodides and bromides). Formation of palladium(0) nanoparticles is observed in the Suzuki and Heck reactions but not in the Sonogashira coupling. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	577-590
Journal	Advanced Synthesis and Catalysis
Volume	350
Issue number	4
DOIs	https://doi.org/10.1002/adsc.200700489
Publication status	Published - 7 Mar 2008

Keywords

C-C coupling
Catalyst immobilization
Organic-inorganic hybrid materials
Palladium
Solgel process

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10.1002/adsc.200700489

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title = "Hybrid organic-inorganic materials from di-(2-pyridyl)methylamine-palladium dichloride complex as recoverable catalysts for Suzuki, Heck and Sonogashira reactions",

abstract = "Hybrid silica materials containing the di-(2-pyridyl)methylamine-palladium dichloride complex, prepared by sol-gel cogelification, are efficient recyclable catalysts for Suzuki (aryl bromides and chlorides), Heck (aryl bromides) and Sonogashira reactions (aryl iodides and bromides). Formation of palladium(0) nanoparticles is observed in the Suzuki and Heck reactions but not in the Sonogashira coupling. {\textcopyright} 2008 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "C-C coupling, Catalyst immobilization, Organic-inorganic hybrid materials, Palladium, Solgel process",

author = "Montserrat Trilla and Roser Pleixats and Man, {Michel Wong Chi} and Catherine Bied and Moreau, {Jo{\"e}l J.E.}",

year = "2008",

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doi = "10.1002/adsc.200700489",

language = "English",

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Hybrid organic-inorganic materials from di-(2-pyridyl)methylamine-palladium dichloride complex as recoverable catalysts for Suzuki, Heck and Sonogashira reactions. / Trilla, Montserrat; Pleixats, Roser; Man, Michel Wong Chi et al.

In: Advanced Synthesis and Catalysis, Vol. 350, No. 4, 07.03.2008, p. 577-590.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Hybrid organic-inorganic materials from di-(2-pyridyl)methylamine-palladium dichloride complex as recoverable catalysts for Suzuki, Heck and Sonogashira reactions

AU - Trilla, Montserrat

AU - Pleixats, Roser

AU - Man, Michel Wong Chi

AU - Bied, Catherine

AU - Moreau, Joël J.E.

PY - 2008/3/7

Y1 - 2008/3/7

N2 - Hybrid silica materials containing the di-(2-pyridyl)methylamine-palladium dichloride complex, prepared by sol-gel cogelification, are efficient recyclable catalysts for Suzuki (aryl bromides and chlorides), Heck (aryl bromides) and Sonogashira reactions (aryl iodides and bromides). Formation of palladium(0) nanoparticles is observed in the Suzuki and Heck reactions but not in the Sonogashira coupling. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - Hybrid silica materials containing the di-(2-pyridyl)methylamine-palladium dichloride complex, prepared by sol-gel cogelification, are efficient recyclable catalysts for Suzuki (aryl bromides and chlorides), Heck (aryl bromides) and Sonogashira reactions (aryl iodides and bromides). Formation of palladium(0) nanoparticles is observed in the Suzuki and Heck reactions but not in the Sonogashira coupling. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - C-C coupling

KW - Catalyst immobilization

KW - Organic-inorganic hybrid materials

KW - Palladium

KW - Solgel process

U2 - 10.1002/adsc.200700489

DO - 10.1002/adsc.200700489

M3 - Article

SN - 1615-4150

VL - 350

SP - 577

EP - 590

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 4

ER -

Hybrid organic-inorganic materials from di-(2-pyridyl)methylamine-palladium dichloride complex as recoverable catalysts for Suzuki, Heck and Sonogashira reactions

Abstract

Keywords

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