Homogeneous catalysis with transition metal complexes containing sulfur ligands

J. C. Bayon; C. Claver; A. M. Masdeu-Bulto

doi:10.1016/S0010-8545(99)00169-1

Homogeneous catalysis with transition metal complexes containing sulfur ligands

J. C. Bayon, C. Claver, A. M. Masdeu-Bulto

Department of Chemistry

Research output: Contribution to journal › Review article › Research › peer-review

185 Citations (Scopus)

Abstract

Transition metal complexes with sulfur ligands are active catalysts in a considerable number of homogeneous reactions, although they have been less investigated than complexes with other donor atoms. We review the application of complexes containing sulfur ligands in hydrogenation, hydrogen transfer, isomerization, hydrosilylation, carbonylation, hydroformylation, polymerization, Heck reaction, allylic alkylation, Grignard cross-coupling, conjugate addition and oxidation with O2. The use of different types of sulfur ligands and the characteristics of the coordination complexes are described together with the results of the catalytic reactions. (C) 1999 Elsevier Science S.A.

Original language	English
Pages (from-to)	73-145
Journal	Coordination Chemistry Reviews
Volume	193-195
DOIs	https://doi.org/10.1016/S0010-8545(99)00169-1
Publication status	Published - 1 Jan 1999

Keywords

Homogenous catalysis
Sulfur ligands
Transition metals

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title = "Homogeneous catalysis with transition metal complexes containing sulfur ligands",

abstract = "Transition metal complexes with sulfur ligands are active catalysts in a considerable number of homogeneous reactions, although they have been less investigated than complexes with other donor atoms. We review the application of complexes containing sulfur ligands in hydrogenation, hydrogen transfer, isomerization, hydrosilylation, carbonylation, hydroformylation, polymerization, Heck reaction, allylic alkylation, Grignard cross-coupling, conjugate addition and oxidation with O2. The use of different types of sulfur ligands and the characteristics of the coordination complexes are described together with the results of the catalytic reactions. (C) 1999 Elsevier Science S.A.",

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AU - Bayon, J. C.

AU - Claver, C.

AU - Masdeu-Bulto, A. M.

PY - 1999/1/1

Y1 - 1999/1/1

N2 - Transition metal complexes with sulfur ligands are active catalysts in a considerable number of homogeneous reactions, although they have been less investigated than complexes with other donor atoms. We review the application of complexes containing sulfur ligands in hydrogenation, hydrogen transfer, isomerization, hydrosilylation, carbonylation, hydroformylation, polymerization, Heck reaction, allylic alkylation, Grignard cross-coupling, conjugate addition and oxidation with O2. The use of different types of sulfur ligands and the characteristics of the coordination complexes are described together with the results of the catalytic reactions. (C) 1999 Elsevier Science S.A.

AB - Transition metal complexes with sulfur ligands are active catalysts in a considerable number of homogeneous reactions, although they have been less investigated than complexes with other donor atoms. We review the application of complexes containing sulfur ligands in hydrogenation, hydrogen transfer, isomerization, hydrosilylation, carbonylation, hydroformylation, polymerization, Heck reaction, allylic alkylation, Grignard cross-coupling, conjugate addition and oxidation with O2. The use of different types of sulfur ligands and the characteristics of the coordination complexes are described together with the results of the catalytic reactions. (C) 1999 Elsevier Science S.A.

KW - Homogenous catalysis

KW - Sulfur ligands

KW - Transition metals

U2 - 10.1016/S0010-8545(99)00169-1

DO - 10.1016/S0010-8545(99)00169-1

M3 - Review article

VL - 193-195

SP - 73

EP - 145

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