Highly selective chromogenic and redox or fluorescent sensors of Hg 2+ in aqueous environment based on 1,4-disubstituted azines

Antonio Caballero; Rosario Martínez; Vega Lloveras; Imma Ratera; José Vidal-Gancedo; Klaus Wurst; Alberto Tárraga; Pedro Molina; Jaume Veciana

doi:10.1021/ja0545766

Highly selective chromogenic and redox or fluorescent sensors of Hg ²⁺ in aqueous environment based on 1,4-disubstituted azines

Antonio Caballero, Rosario Martínez, Vega Lloveras, Imma Ratera, José Vidal-Gancedo, Klaus Wurst, Alberto Tárraga, Pedro Molina, Jaume Veciana

Research output: Contribution to journal › Article › Research › peer-review

446 Citations (Scopus)

Abstract

Two new chemosensors that exhibit high affinity and high selectivity for Hg2+ in aqueous environment which operate through two different channels, optic/redox and optic/fluorescent, are reported. The optical change in sensing can be used even for a "naked-eye" detection of Hg2+ ions, whereas the fluorescent response can be modulated by varying the solvent polarity. Copyright © 2005 American Chemical Society.

Original language	English
Pages (from-to)	15666-15667
Journal	Journal of the American Chemical Society
Volume	127
Issue number	45
DOIs	https://doi.org/10.1021/ja0545766
Publication status	Published - 16 Nov 2005

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Caballero, Antonio ; Martínez, Rosario ; Lloveras, Vega ; Ratera, Imma ; Vidal-Gancedo, José ; Wurst, Klaus ; Tárraga, Alberto ; Molina, Pedro ; Veciana, Jaume. / Highly selective chromogenic and redox or fluorescent sensors of Hg ²⁺ in aqueous environment based on 1,4-disubstituted azines. In: Journal of the American Chemical Society. 2005 ; Vol. 127, No. 45. pp. 15666-15667.

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title = "Highly selective chromogenic and redox or fluorescent sensors of Hg 2+ in aqueous environment based on 1,4-disubstituted azines",

abstract = "Two new chemosensors that exhibit high affinity and high selectivity for Hg2+ in aqueous environment which operate through two different channels, optic/redox and optic/fluorescent, are reported. The optical change in sensing can be used even for a {"}naked-eye{"} detection of Hg2+ ions, whereas the fluorescent response can be modulated by varying the solvent polarity. Copyright {\textcopyright} 2005 American Chemical Society.",

author = "Antonio Caballero and Rosario Mart{\'i}nez and Vega Lloveras and Imma Ratera and Jos{\'e} Vidal-Gancedo and Klaus Wurst and Alberto T{\'a}rraga and Pedro Molina and Jaume Veciana",

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Highly selective chromogenic and redox or fluorescent sensors of Hg ²⁺ in aqueous environment based on 1,4-disubstituted azines. / Caballero, Antonio; Martínez, Rosario; Lloveras, Vega; Ratera, Imma; Vidal-Gancedo, José; Wurst, Klaus; Tárraga, Alberto; Molina, Pedro; Veciana, Jaume.

In: Journal of the American Chemical Society, Vol. 127, No. 45, 16.11.2005, p. 15666-15667.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Highly selective chromogenic and redox or fluorescent sensors of Hg 2+ in aqueous environment based on 1,4-disubstituted azines

AU - Caballero, Antonio

AU - Martínez, Rosario

AU - Lloveras, Vega

AU - Ratera, Imma

AU - Vidal-Gancedo, José

AU - Wurst, Klaus

AU - Tárraga, Alberto

AU - Molina, Pedro

AU - Veciana, Jaume

PY - 2005/11/16

Y1 - 2005/11/16

N2 - Two new chemosensors that exhibit high affinity and high selectivity for Hg2+ in aqueous environment which operate through two different channels, optic/redox and optic/fluorescent, are reported. The optical change in sensing can be used even for a "naked-eye" detection of Hg2+ ions, whereas the fluorescent response can be modulated by varying the solvent polarity. Copyright © 2005 American Chemical Society.

AB - Two new chemosensors that exhibit high affinity and high selectivity for Hg2+ in aqueous environment which operate through two different channels, optic/redox and optic/fluorescent, are reported. The optical change in sensing can be used even for a "naked-eye" detection of Hg2+ ions, whereas the fluorescent response can be modulated by varying the solvent polarity. Copyright © 2005 American Chemical Society.

U2 - 10.1021/ja0545766

DO - 10.1021/ja0545766

M3 - Article

VL - 127

SP - 15666

EP - 15667

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 45

ER -

Highly selective chromogenic and redox or fluorescent sensors of Hg 2+ in aqueous environment based on 1,4-disubstituted azines

Abstract

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Highly selective chromogenic and redox or fluorescent sensors of Hg ²⁺ in aqueous environment based on 1,4-disubstituted azines