Highly efficient and stereocontrolled synthetic route to enantiopure ACC derivatives. Synthesis of (+)-N-benzyloxycarbonyl-γ,δ-dehydro-allo-coronamic acid methyl ester

José M. Jiménez, Ramon Casas, Rosa M. Ortuño

Research output: Contribution to journalArticleResearchpeer-review

20 Citations (Scopus)

Abstract

Highly diastereoselective cyclopropanation of a chiral α,β-dehydroamino acid derivative, obtained from D-mannitol, leads to a single isomer which has been transformed into the title compound in 65% overall yield. This product can be a useful intermediate in the synthesis of enantiopure ACC derivatives. © 1994.
Original languageEnglish
Pages (from-to)5945-5948
JournalTetrahedron Letters
Volume35
Issue number32
Publication statusPublished - 8 Aug 1994

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