Hexakis(silyl)palladium(VI) or palladium(II) with η2-disilane ligands?

Gabriel Aullón, Agustí Lledós, Santiago Alvarez

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Side-bound Si-Si single bonds: A theoretical study indicates that in a recently reported compound, two Si-Si bonds are side-on coordinated to a square-planar PdII ion (see picture).
Original languageEnglish
Pages (from-to)1956-1959
JournalAngewandte Chemie - International Edition
Volume41
Issue number11
DOIs
Publication statusPublished - 3 Jun 2002

Keywords

  • Agostic interactions
  • Density functional calculations
  • Electronic structure
  • Palladium
  • Si ligands

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