Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformation

Jorge Albalad, Javier Aríñez-Soriano, José Vidal-Gancedo, Vega Lloveras, Jordi Juanhuix, Inhar Imaz, Núria Aliaga-Alcalde, Daniel Maspoch

    Research output: Contribution to journalArticleResearchpeer-review

    12 Citations (Scopus)

    Abstract

    © 2016 The Royal Society of Chemistry. Herein we report a water-induced single-crystal to single-crystal transformation that involves the formation of hetero-bimetallic paddlewheel clusters in coordination polymers. Through this transformation, which involves the cleavage and formation of different coordination bonds, two different Cu(ii)-Zn(ii) and Cu(ii)-Ni(ii) paddlewheel units exhibiting a 1:1 metal ratio were created.
    Original languageEnglish
    Pages (from-to)13397-13400
    JournalChemical Communications
    Volume52
    Issue number91
    DOIs
    Publication statusPublished - 1 Jan 2016

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