H-H Bond Activation

R. Mas-Ballesté; A. Lledós

doi:10.1016/B978-0-08-097774-4.00931-1

H-H Bond Activation

R. Mas-Ballesté, A. Lledós

Department of Chemistry

Research output: Chapter in Book › Chapter › Research › peer-review

11 Citations (Scopus)

Abstract

Dihydrogen is an essentially inert molecule that needs to be activated to take part in chemical transformations. This chapter outlines, with a mechanistic perspective, the pathways for the H-H bond-breaking/bond-forming processes, analyzing the species along these pathways (dihydrogen complexes, dihydrides, and monohydrides) and their interrelations. This chapter focuses on results collected between 2001 and 2011. The interplay between theory and experiment has been particularly beneficial in advancing the understanding of dihydrogen chemistry and is stressed throughout the chapter. © 2013 Elsevier Ltd. All rights reserved.

Original language	English
Title of host publication	Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications
Pages	727-766
Number of pages	39
Volume	9
DOIs	https://doi.org/10.1016/B978-0-08-097774-4.00931-1
Publication status	Published - 1 Aug 2013

Keywords

Compressed dihydride complexes
Dihydrogen bonding
Dihydrogen complexes
Elongated dihydrogen complexes
Heterolytic splitting
Homolytic splitting
Hydride metal complexes
Hydride protonation
Hydrogen activation
Hydrogenation mechanisms
Metal-free hydrogen activation
Theoretical calculations

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title = "H-H Bond Activation",

abstract = "Dihydrogen is an essentially inert molecule that needs to be activated to take part in chemical transformations. This chapter outlines, with a mechanistic perspective, the pathways for the H-H bond-breaking/bond-forming processes, analyzing the species along these pathways (dihydrogen complexes, dihydrides, and monohydrides) and their interrelations. This chapter focuses on results collected between 2001 and 2011. The interplay between theory and experiment has been particularly beneficial in advancing the understanding of dihydrogen chemistry and is stressed throughout the chapter. {\textcopyright} 2013 Elsevier Ltd. All rights reserved.",

keywords = "Compressed dihydride complexes, Dihydrogen bonding, Dihydrogen complexes, Elongated dihydrogen complexes, Heterolytic splitting, Homolytic splitting, Hydride metal complexes, Hydride protonation, Hydrogen activation, Hydrogenation mechanisms, Metal-free hydrogen activation, Theoretical calculations",

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doi = "10.1016/B978-0-08-097774-4.00931-1",

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T1 - H-H Bond Activation

AU - Mas-Ballesté, R.

AU - Lledós, A.

PY - 2013/8/1

Y1 - 2013/8/1

N2 - Dihydrogen is an essentially inert molecule that needs to be activated to take part in chemical transformations. This chapter outlines, with a mechanistic perspective, the pathways for the H-H bond-breaking/bond-forming processes, analyzing the species along these pathways (dihydrogen complexes, dihydrides, and monohydrides) and their interrelations. This chapter focuses on results collected between 2001 and 2011. The interplay between theory and experiment has been particularly beneficial in advancing the understanding of dihydrogen chemistry and is stressed throughout the chapter. © 2013 Elsevier Ltd. All rights reserved.

AB - Dihydrogen is an essentially inert molecule that needs to be activated to take part in chemical transformations. This chapter outlines, with a mechanistic perspective, the pathways for the H-H bond-breaking/bond-forming processes, analyzing the species along these pathways (dihydrogen complexes, dihydrides, and monohydrides) and their interrelations. This chapter focuses on results collected between 2001 and 2011. The interplay between theory and experiment has been particularly beneficial in advancing the understanding of dihydrogen chemistry and is stressed throughout the chapter. © 2013 Elsevier Ltd. All rights reserved.

KW - Compressed dihydride complexes

KW - Dihydrogen bonding

KW - Dihydrogen complexes

KW - Elongated dihydrogen complexes

KW - Heterolytic splitting

KW - Homolytic splitting

KW - Hydride metal complexes

KW - Hydride protonation

KW - Hydrogen activation

KW - Hydrogenation mechanisms

KW - Metal-free hydrogen activation

KW - Theoretical calculations

U2 - 10.1016/B978-0-08-097774-4.00931-1

DO - 10.1016/B978-0-08-097774-4.00931-1

M3 - Chapter

SN - 9780080965291

VL - 9

SP - 727

EP - 766

BT - Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications

ER -