Gold-catalyzed [4C+3C] intramolecular cycloaddition of allenedienes: Synthetic potential and mechanistic implications

Keyphrases

• Cycloaddition 100%
• Au Complex 100%
• Cycloadducts 100%
• Gold-catalyzed 100%
• Mechanistic Implication 100%
• Intramolecular Cyclization 100%
• In Situ 50%
• Room Temperature 50%
• Alkyl 50%
• Carbenes 50%
• Good Yield 50%
• N-heterocyclic Carbenes 50%
• Low Energy Barrier 50%
• AgSbF6 50%
• NMR Monitoring 50%
• AuCl3 50%
• Tricycle 50%
• Au Catalyst 50%

Chemistry

• Cycloaddition 100%
• Intramolecular Cycloaddition 100%
• Energy Barrier 50%
• N-Heterocyclic Carbene 50%
• NMR Spectroscopy 50%
• Ambient Reaction Temperature 50%
• Carbene 50%