TY - JOUR
T1 - From p-benzoquinone to cyclohexane chirons: First asymmetric synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide
AU - Busqué, Felix
AU - Cantó, Mariona
AU - De March, Pedro
AU - Figueredo, Marta
AU - Font, Josep
AU - Rodríguez, Sonia
PY - 2003/7/18
Y1 - 2003/7/18
N2 - Starting from a common, easily available, enantiopure monoketal of p-benzoquinone, the synthesis of a large number of cyclohexane chirons has been achieved. The first synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide has been performed from one of these new building blocks. The wide variety of functional groups of this series of chirons makes them useful for subsequent synthetic processes. © 2003 Elsevier Science Ltd. All rights reserved.
AB - Starting from a common, easily available, enantiopure monoketal of p-benzoquinone, the synthesis of a large number of cyclohexane chirons has been achieved. The first synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide has been performed from one of these new building blocks. The wide variety of functional groups of this series of chirons makes them useful for subsequent synthetic processes. © 2003 Elsevier Science Ltd. All rights reserved.
U2 - 10.1016/S0957-4166(03)00357-4
DO - 10.1016/S0957-4166(03)00357-4
M3 - Article
SN - 0957-4166
VL - 14
SP - 2021
EP - 2032
JO - Tetrahedron Asymmetry
JF - Tetrahedron Asymmetry
IS - 14
ER -