Formation of 1:1, 2:1, and 2:2 Complexes between Carbonyl Compounds and Titanium Tetrachloride. An ab Initio Study

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Abstract

The complexes of formaldehyde, acetaldehyde, and acetone with titanium tetrachloride of stoichiometrics 1:1, 2:1, and 2:2 have been studied with ab initio SCF-MO methods. The competition between the formation of the 2:1 and 2:2 complexes has been analyzed, and the role of the steric effects has been discussed. © 1995, American Chemical Society. All rights reserved.
Original languageEnglish
Pages (from-to)3433-3439
JournalInorg. Chem.
Volume34
Issue number13
DOIs
Publication statusPublished - 1 Jun 1995

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