The complexes of formaldehyde, acetaldehyde, and acetone with titanium tetrachloride of stoichiometrics 1:1, 2:1, and 2:2 have been studied with ab initio SCF-MO methods. The competition between the formation of the 2:1 and 2:2 complexes has been analyzed, and the role of the steric effects has been discussed. © 1995, American Chemical Society. All rights reserved.
|Publication status||Published - 1 Jun 1995|