Fluorous aryl compounds by Matsuda-Heck reaction

Jordi Salabert, Rosa María Sebastián, Adelina Vallribera, Anna Roglans, Carmen Nájera

Research output: Contribution to journalArticleResearchpeer-review

17 Citations (Scopus)

Abstract

Fluorous aryl compounds are obtained through the arylation of different electron-rich and electron-poor olefins with an arenediazonium salt bearing a fully fluorinated octyl-ponytail at the para position. The Matsuda-Heck reactions are catalyzed by Pd(OAc)2 or 4-hydroxyacetophenone oxime-derived palladacycle as efficient sources of Pd nanoparticles, with loadings of 1 mol % Pd, at room temperature, in methanol and without the need to add external base. © 2011 Elsevier Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)8659-8664
JournalTetrahedron
Volume67
Issue number45
DOIs
Publication statusPublished - 11 Nov 2011

Keywords

  • Arenediazonium salt
  • Fluorous compounds
  • Matsuda-Heck
  • Nanoparticles
  • Palladacycle
  • Palladium

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