Facile, fast and green synthesis of a highly porous calcium-syringate bioMOF with intriguing triple bioactivity

Albert Rosado; Oriol Vallcorba; Blanca Vázquez-Lasa; Luís García-Fernández; Rosa Ana Ramírez-Jiménez; María Rosa Aguilar; Ana M. López-Periago; Concepción Domingo; José A. Ayllón

doi:10.1039/d2qi02639b

Facile, fast and green synthesis of a highly porous calcium-syringate bioMOF with intriguing triple bioactivity

Albert Rosado, Oriol Vallcorba, Blanca Vázquez-Lasa, Luís García-Fernández, Rosa Ana Ramírez-Jiménez, María Rosa Aguilar, Ana M. López-Periago, Concepción Domingo, José A. Ayllón

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

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Abstract

A facile, fast and green strategy based on ethanol is utilized to prepare a new bioMOF, namely, CaSyr-1, with particular characteristics of full biocompatibility given by using just calcium and syringic acid, the latter being a phenolic natural product found in fruits and vegetables, permanent porosity with an outstanding surface area >1000 m ² g ⁻¹, and a micropore diameter of 1.4 nm close to mesopore values. Collectively, these data establish CaSyr-1 as one of the most porous bioMOFs reported to date, with high molecular adsorption capacity. The CaSyr-1 adsorptive behavior is revised here through the reversible adsorption of CO ₂ and the encapsulation of bioactive ingredients in the structure. Remarkably, CaSyr-1 enables the development of triple therapeutic entities, involving bioactive Ca ²⁺, syringic acid and an impregnated drug.

Original language	English
Pages (from-to)	2165–2173
Number of pages	9
Journal	Inorganic Chemistry Frontiers
Volume	10
Issue number	7
DOIs	https://doi.org/10.1039/d2qi02639b
Publication status	Published - 2 Mar 2023

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Rosado, A., Vallcorba, O., Vázquez-Lasa, B., García-Fernández, L., Ramírez-Jiménez, R. A., Aguilar, M. R., López-Periago, A. M., Domingo, C., & Ayllón, J. A. (2023). Facile, fast and green synthesis of a highly porous calcium-syringate bioMOF with intriguing triple bioactivity. Inorganic Chemistry Frontiers, 10(7), 2165–2173. https://doi.org/10.1039/d2qi02639b

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abstract = "A facile, fast and green strategy based on ethanol is utilized to prepare a new bioMOF, namely, CaSyr-1, with particular characteristics of full biocompatibility given by using just calcium and syringic acid, the latter being a phenolic natural product found in fruits and vegetables, permanent porosity with an outstanding surface area >1000 m 2 g −1, and a micropore diameter of 1.4 nm close to mesopore values. Collectively, these data establish CaSyr-1 as one of the most porous bioMOFs reported to date, with high molecular adsorption capacity. The CaSyr-1 adsorptive behavior is revised here through the reversible adsorption of CO 2 and the encapsulation of bioactive ingredients in the structure. Remarkably, CaSyr-1 enables the development of triple therapeutic entities, involving bioactive Ca 2+, syringic acid and an impregnated drug.",

author = "Albert Rosado and Oriol Vallcorba and Blanca V{\'a}zquez-Lasa and Lu{\'i}s Garc{\'i}a-Fern{\'a}ndez and Ram{\'i}rez-Jim{\'e}nez, {Rosa Ana} and Aguilar, {Mar{\'i}a Rosa} and L{\'o}pez-Periago, {Ana M.} and Concepci{\'o}n Domingo and Ayll{\'o}n, {Jos{\'e} A.}",

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doi = "10.1039/d2qi02639b",

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T1 - Facile, fast and green synthesis of a highly porous calcium-syringate bioMOF with intriguing triple bioactivity

AU - Rosado, Albert

AU - Vallcorba, Oriol

AU - Vázquez-Lasa, Blanca

AU - García-Fernández, Luís

AU - Ramírez-Jiménez, Rosa Ana

AU - Aguilar, María Rosa

AU - López-Periago, Ana M.

AU - Domingo, Concepción

AU - Ayllón, José A.

PY - 2023/3/2

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AB - A facile, fast and green strategy based on ethanol is utilized to prepare a new bioMOF, namely, CaSyr-1, with particular characteristics of full biocompatibility given by using just calcium and syringic acid, the latter being a phenolic natural product found in fruits and vegetables, permanent porosity with an outstanding surface area >1000 m 2 g −1, and a micropore diameter of 1.4 nm close to mesopore values. Collectively, these data establish CaSyr-1 as one of the most porous bioMOFs reported to date, with high molecular adsorption capacity. The CaSyr-1 adsorptive behavior is revised here through the reversible adsorption of CO 2 and the encapsulation of bioactive ingredients in the structure. Remarkably, CaSyr-1 enables the development of triple therapeutic entities, involving bioactive Ca 2+, syringic acid and an impregnated drug.

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Facile, fast and green synthesis of a highly porous calcium-syringate bioMOF with intriguing triple bioactivity

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