Extractive-spectrophotometric determination of traces of copper(II) with 4-(p-nitrophenylazo)-2-amino-3-pyridinol

M. Salillas, P. Tarín, M. Blanco

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3 Citations (Scopus)

Abstract

A new extractive-spectrophotometric method for determination of copper(II) with 4-(p-nitrophenylazo)-2-amino-3-pyridinol is proposed. The established stoichiometry and extraction constant are 2:1 ligand:metal and -1.55, respectively. The molar absorptivity of the complex is 5.19 × 104 liters mol-1 cm-1 at 560 nm and Sandell's sensitivity is 1.2 ng cm-2. The best conditions for determination and effect of other ions are studied. The method proposed is applied in the determination of copper in whisky, liver of fish, and seawater. © 1985.
Original languageEnglish
Pages (from-to)61-69
JournalMicrochemical Journal
Volume31
Issue number1
DOIs
Publication statusPublished - 1 Jan 1985

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