Extended linear metal-metal interactions in an anionic rhodium(I) complex. X-ray structure of NMe<inf>4</inf>[Rh(ox)(CO)<inf>2</inf>] (ox = oxalato)

Julio Real; J. Carles Bayón; Fernando J. Lahoz; José A. López

doi:10.1039/C39890001889

Extended linear metal-metal interactions in an anionic rhodium(I) complex. X-ray structure of NMe<inf>4</inf>[Rh(ox)(CO)<inf>2</inf>] (ox = oxalato)

Julio Real, J. Carles Bayón, Fernando J. Lahoz, José A. López

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

16 Citations (Scopus)

Abstract

The complex NMe4[Rh(ox)(CO)2] (2) (ox = oxalato) was prepared from NMe4[Rh(ox)(cod)] (1) (cod=cyclo-octa-1,5-diene) by bubbling carbon monoxide and, complex (1) was prepared from Rh 2Cl2(cod)2, oxalic acid, and NMe4OH; the solid state structure of (2) consists of infinite chains of metal atoms [Rh ⋯ Rh ⋯ Rh 175.01(3)°] with equal rhodium-rhodium distances of 3.243(1) Å, the shortest distance found in a stacked rhodium complex.

Original language	English
Pages (from-to)	1889-1890
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39890001889
Publication status	Published - 1 Jan 1989

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@article{3580203aa1324135b6399c5853fb0f49,

title = "Extended linear metal-metal interactions in an anionic rhodium(I) complex. X-ray structure of NMe4[Rh(ox)(CO)2] (ox = oxalato)",

abstract = "The complex NMe4[Rh(ox)(CO)2] (2) (ox = oxalato) was prepared from NMe4[Rh(ox)(cod)] (1) (cod=cyclo-octa-1,5-diene) by bubbling carbon monoxide and, complex (1) was prepared from Rh 2Cl2(cod)2, oxalic acid, and NMe4OH; the solid state structure of (2) consists of infinite chains of metal atoms [Rh ⋯ Rh ⋯ Rh 175.01(3)°] with equal rhodium-rhodium distances of 3.243(1) {\AA}, the shortest distance found in a stacked rhodium complex.",

author = "Julio Real and Bay{\'o}n, {J. Carles} and Lahoz, {Fernando J.} and L{\'o}pez, {Jos{\'e} A.}",

year = "1989",

month = jan,

day = "1",

doi = "10.1039/C39890001889",

language = "English",

pages = "1889--1890",

number = "24",

}

Extended linear metal-metal interactions in an anionic rhodium(I) complex. X-ray structure of NMe<inf>4</inf>[Rh(ox)(CO)<inf>2</inf>] (ox = oxalato). / Real, Julio; Bayón, J. Carles; Lahoz, Fernando J.; López, José A.

In: Journal of the Chemical Society, Chemical Communications, No. 24, 01.01.1989, p. 1889-1890.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Extended linear metal-metal interactions in an anionic rhodium(I) complex. X-ray structure of NMe4[Rh(ox)(CO)2] (ox = oxalato)

AU - Real, Julio

AU - Bayón, J. Carles

AU - Lahoz, Fernando J.

AU - López, José A.

PY - 1989/1/1

Y1 - 1989/1/1

N2 - The complex NMe4[Rh(ox)(CO)2] (2) (ox = oxalato) was prepared from NMe4[Rh(ox)(cod)] (1) (cod=cyclo-octa-1,5-diene) by bubbling carbon monoxide and, complex (1) was prepared from Rh 2Cl2(cod)2, oxalic acid, and NMe4OH; the solid state structure of (2) consists of infinite chains of metal atoms [Rh ⋯ Rh ⋯ Rh 175.01(3)°] with equal rhodium-rhodium distances of 3.243(1) Å, the shortest distance found in a stacked rhodium complex.

AB - The complex NMe4[Rh(ox)(CO)2] (2) (ox = oxalato) was prepared from NMe4[Rh(ox)(cod)] (1) (cod=cyclo-octa-1,5-diene) by bubbling carbon monoxide and, complex (1) was prepared from Rh 2Cl2(cod)2, oxalic acid, and NMe4OH; the solid state structure of (2) consists of infinite chains of metal atoms [Rh ⋯ Rh ⋯ Rh 175.01(3)°] with equal rhodium-rhodium distances of 3.243(1) Å, the shortest distance found in a stacked rhodium complex.

U2 - 10.1039/C39890001889

DO - 10.1039/C39890001889

M3 - Article

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