Exploring the reactivity of an N-pyrazole, P-phosphine hybrid ligand with Cu(I), Ag(I) and Au(I) precursors

Sergio Muñoz, Josefina Pons, Josep Ros, Colin A. Kilner, Malcolm A. Halcrow

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11 Citations (Scopus)

Abstract

The reactivity of (3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenylphosphine (L) hybrid ligand against Cu(I), Ag(I) and Au(I) has been assayed and compounds [Cu(L)2](PF6) (1), [Ag(L)]2(PF 6)2·2C2H4Cl 2·2C4H10O (2) and [AuCl(L)]2 (3) have been isolated and fully characterised. A fully characterisation by analytical and spectroscopic methods of 1-3 are presented and X-ray crystal structures of 1 and 2 are also reported. The similar data obtained between 2 and 3 permits to do a serious purpose of the structure of 3 in solid and solution. © 2011 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)2736-2741
JournalJournal of Organometallic Chemistry
Volume696
Issue number14
DOIs
Publication statusPublished - 15 Jul 2011

Keywords

  • Copper(I)
  • Gold(I)
  • N,P-Hybrid ligand
  • Phosphine
  • Silver(I)
  • X-ray crystal structures

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