Exploring the reactivity of an N-pyrazole, P-phosphine hybrid ligand with Cu(I), Ag(I) and Au(I) precursors

Sergio Muñoz; Josefina Pons; Josep Ros; Colin A. Kilner; Malcolm A. Halcrow

doi:10.1016/j.jorganchem.2011.04.019

Exploring the reactivity of an N-pyrazole, P-phosphine hybrid ligand with Cu(I), Ag(I) and Au(I) precursors

Sergio Muñoz, Josefina Pons, Josep Ros, Colin A. Kilner, Malcolm A. Halcrow

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

11 Citations (Scopus)

Abstract

The reactivity of (3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenylphosphine (L) hybrid ligand against Cu(I), Ag(I) and Au(I) has been assayed and compounds [Cu(L)2](PF6) (1), [Ag(L)]2(PF 6)2·2C2H4Cl 2·2C4H10O (2) and [AuCl(L)]2 (3) have been isolated and fully characterised. A fully characterisation by analytical and spectroscopic methods of 1-3 are presented and X-ray crystal structures of 1 and 2 are also reported. The similar data obtained between 2 and 3 permits to do a serious purpose of the structure of 3 in solid and solution. © 2011 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	2736-2741
Journal	Journal of Organometallic Chemistry
Volume	696
Issue number	14
DOIs	https://doi.org/10.1016/j.jorganchem.2011.04.019
Publication status	Published - 15 Jul 2011

Keywords

Copper(I)
Gold(I)
N,P-Hybrid ligand
Phosphine
Silver(I)
X-ray crystal structures

Access to Document

10.1016/j.jorganchem.2011.04.019

Fingerprint Dive into the research topics of 'Exploring the reactivity of an N-pyrazole, P-phosphine hybrid ligand with Cu(I), Ag(I) and Au(I) precursors'. Together they form a unique fingerprint.

Cite this

@article{b6d09f9b9e314693ad4a4be45b8fe2fc,

title = "Exploring the reactivity of an N-pyrazole, P-phosphine hybrid ligand with Cu(I), Ag(I) and Au(I) precursors",

abstract = "The reactivity of (3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenylphosphine (L) hybrid ligand against Cu(I), Ag(I) and Au(I) has been assayed and compounds [Cu(L)2](PF6) (1), [Ag(L)]2(PF 6)2·2C2H4Cl 2·2C4H10O (2) and [AuCl(L)]2 (3) have been isolated and fully characterised. A fully characterisation by analytical and spectroscopic methods of 1-3 are presented and X-ray crystal structures of 1 and 2 are also reported. The similar data obtained between 2 and 3 permits to do a serious purpose of the structure of 3 in solid and solution. {\textcopyright} 2011 Elsevier B.V. All rights reserved.",

keywords = "Copper(I), Gold(I), N,P-Hybrid ligand, Phosphine, Silver(I), X-ray crystal structures",

author = "Sergio Mu{\~n}oz and Josefina Pons and Josep Ros and Kilner, {Colin A.} and Halcrow, {Malcolm A.}",

year = "2011",

month = jul,

day = "15",

doi = "10.1016/j.jorganchem.2011.04.019",

language = "English",

volume = "696",

pages = "2736--2741",

number = "14",

}

TY - JOUR

T1 - Exploring the reactivity of an N-pyrazole, P-phosphine hybrid ligand with Cu(I), Ag(I) and Au(I) precursors

AU - Muñoz, Sergio

AU - Pons, Josefina

AU - Ros, Josep

AU - Kilner, Colin A.

AU - Halcrow, Malcolm A.

PY - 2011/7/15

Y1 - 2011/7/15

N2 - The reactivity of (3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenylphosphine (L) hybrid ligand against Cu(I), Ag(I) and Au(I) has been assayed and compounds [Cu(L)2](PF6) (1), [Ag(L)]2(PF 6)2·2C2H4Cl 2·2C4H10O (2) and [AuCl(L)]2 (3) have been isolated and fully characterised. A fully characterisation by analytical and spectroscopic methods of 1-3 are presented and X-ray crystal structures of 1 and 2 are also reported. The similar data obtained between 2 and 3 permits to do a serious purpose of the structure of 3 in solid and solution. © 2011 Elsevier B.V. All rights reserved.

AB - The reactivity of (3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenylphosphine (L) hybrid ligand against Cu(I), Ag(I) and Au(I) has been assayed and compounds [Cu(L)2](PF6) (1), [Ag(L)]2(PF 6)2·2C2H4Cl 2·2C4H10O (2) and [AuCl(L)]2 (3) have been isolated and fully characterised. A fully characterisation by analytical and spectroscopic methods of 1-3 are presented and X-ray crystal structures of 1 and 2 are also reported. The similar data obtained between 2 and 3 permits to do a serious purpose of the structure of 3 in solid and solution. © 2011 Elsevier B.V. All rights reserved.

KW - Copper(I)

KW - Gold(I)

KW - N,P-Hybrid ligand

KW - Phosphine

KW - Silver(I)

KW - X-ray crystal structures

U2 - 10.1016/j.jorganchem.2011.04.019

DO - 10.1016/j.jorganchem.2011.04.019

M3 - Article

VL - 696

SP - 2736

EP - 2741

IS - 14

ER -