Exploring a novel preparation method of 1D metal organic frameworks based on supercritical CO2

A. López-Periago, O. Vallcorba, C. Frontera, C. Domingo, J. A. Ayllón

Research output: Contribution to journalArticleResearchpeer-review

21 Citations (Scopus)

Abstract

© The Royal Society of Chemistry 2015. The preparation of copper(II) one-dimensional MOFs using an eco-efficient method is reported here. This method is based exclusively on using supercritical CO2 as a solvent, without the addition of any other additive or co-solvent. Neutral acetylacetonate copper complexes and two linear linkers, namely, the bidentate 4,4′-bipyridine and 4,4′-trimethylenedipyridine molecules, were reacted under compressed CO2 at 60 °C and 20 MPa for periods of 4 or 24 h. The success achieved in the synthesis of the different studied 1D-MOFs was related to the solubility of the reagents in supercritical CO2. The reaction yield of the synthesized coordination polymers via the supercritical route was close to 100% because both the reactants were almost completely depleted in the performed experiments.
Original languageEnglish
Pages (from-to)7548-7553
JournalDalton Transactions
Volume44
Issue number16
DOIs
Publication statusPublished - 28 Apr 2015

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