Ene reactions between two alkynes? Doors open to thermally induced cycloisomerization of macrocyclic triynes and enediynes

Iván González, Anna Pla-Quintana, Anna Roglans, Anna Dachs, Miquel Solà, Teodor Parella, Jordi Farjas, Pere Roura, Vega Lloveras, José Vidal-Gancedo

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Abstract

A domino process is described combining an ene reaction between two alkynes and a Diels-Alder cycloaddition of the vinylallene formed. The process accounts for the thermally induced cycloisomerization of macrocyclic triynes and enediynes to give fused tetracycles in a stereoselective manner. © The Royal Society of Chemistry 2010.
Original languageEnglish
Pages (from-to)2944-2946
JournalChemical Communications
Volume46
Issue number17
DOIs
Publication statusPublished - 1 Jan 2010

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    González, I., Pla-Quintana, A., Roglans, A., Dachs, A., Solà, M., Parella, T., Farjas, J., Roura, P., Lloveras, V., & Vidal-Gancedo, J. (2010). Ene reactions between two alkynes? Doors open to thermally induced cycloisomerization of macrocyclic triynes and enediynes. Chemical Communications, 46(17), 2944-2946. https://doi.org/10.1039/b926497c