Ene reactions between two alkynes? Doors open to thermally induced cycloisomerization of macrocyclic triynes and enediynes

Iván González; Anna Pla-Quintana; Anna Roglans; Anna Dachs; Miquel Solà; Teodor Parella; Jordi Farjas; Pere Roura; Vega Lloveras; José Vidal-Gancedo

doi:10.1039/b926497c

Ene reactions between two alkynes? Doors open to thermally induced cycloisomerization of macrocyclic triynes and enediynes

Iván González, Anna Pla-Quintana, Anna Roglans, Anna Dachs, Miquel Solà, Teodor Parella, Jordi Farjas, Pere Roura, Vega Lloveras, José Vidal-Gancedo

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

22 Citations (Scopus)

Abstract

A domino process is described combining an ene reaction between two alkynes and a Diels-Alder cycloaddition of the vinylallene formed. The process accounts for the thermally induced cycloisomerization of macrocyclic triynes and enediynes to give fused tetracycles in a stereoselective manner. © The Royal Society of Chemistry 2010.

Original language	English
Pages (from-to)	2944-2946
Journal	Chemical Communications
Volume	46
Issue number	17
DOIs	https://doi.org/10.1039/b926497c
Publication status	Published - 1 Jan 2010

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abstract = "A domino process is described combining an ene reaction between two alkynes and a Diels-Alder cycloaddition of the vinylallene formed. The process accounts for the thermally induced cycloisomerization of macrocyclic triynes and enediynes to give fused tetracycles in a stereoselective manner. {\textcopyright} The Royal Society of Chemistry 2010.",

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T1 - Ene reactions between two alkynes? Doors open to thermally induced cycloisomerization of macrocyclic triynes and enediynes

AU - González, Iván

AU - Pla-Quintana, Anna

AU - Roglans, Anna

AU - Dachs, Anna

AU - Solà, Miquel

AU - Parella, Teodor

AU - Farjas, Jordi

AU - Roura, Pere

AU - Lloveras, Vega

AU - Vidal-Gancedo, José

PY - 2010/1/1

Y1 - 2010/1/1

N2 - A domino process is described combining an ene reaction between two alkynes and a Diels-Alder cycloaddition of the vinylallene formed. The process accounts for the thermally induced cycloisomerization of macrocyclic triynes and enediynes to give fused tetracycles in a stereoselective manner. © The Royal Society of Chemistry 2010.

AB - A domino process is described combining an ene reaction between two alkynes and a Diels-Alder cycloaddition of the vinylallene formed. The process accounts for the thermally induced cycloisomerization of macrocyclic triynes and enediynes to give fused tetracycles in a stereoselective manner. © The Royal Society of Chemistry 2010.

U2 - 10.1039/b926497c

DO - 10.1039/b926497c

M3 - Article

VL - 46

SP - 2944

EP - 2946

IS - 17

ER -

Ene reactions between two alkynes? Doors open to thermally induced cycloisomerization of macrocyclic triynes and enediynes

Abstract

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