Ene reactions between two alkynes? Doors open to thermally induced cycloisomerization of macrocyclic triynes and enediynes

Iván González, Anna Pla-Quintana, Anna Roglans, Anna Dachs, Miquel Solà, Teodor Parella, Jordi Farjas, Pere Roura, Vega Lloveras, José Vidal-Gancedo

Research output: Contribution to journalArticleResearchpeer-review

21 Citations (Scopus)

Abstract

A domino process is described combining an ene reaction between two alkynes and a Diels-Alder cycloaddition of the vinylallene formed. The process accounts for the thermally induced cycloisomerization of macrocyclic triynes and enediynes to give fused tetracycles in a stereoselective manner. © The Royal Society of Chemistry 2010.
Original languageEnglish
Pages (from-to)2944-2946
JournalChemical Communications
Volume46
Issue number17
DOIs
Publication statusPublished - 1 Jan 2010

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