Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

Marcial Moreno-Mañas; Jordi Ribas

doi:10.1016/S0040-4039(00)99415-2

Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

Marcial Moreno-Mañas, Jordi Ribas

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

17 Citations (Scopus)

Abstract

A high regioselectivity has been observed in the palladium catalyzed allylation of "soft" nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. © 1989.

Original language	English
Pages (from-to)	3109-3112
Journal	Tetrahedron Letters
Volume	30
Issue number	23
DOIs	https://doi.org/10.1016/S0040-4039(00)99415-2
Publication status	Published - 1 Jan 1989

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title = "Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes",

abstract = "A high regioselectivity has been observed in the palladium catalyzed allylation of {"}soft{"} nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. {\textcopyright} 1989.",

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AU - Moreno-Mañas, Marcial

AU - Ribas, Jordi

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N2 - A high regioselectivity has been observed in the palladium catalyzed allylation of "soft" nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. © 1989.

AB - A high regioselectivity has been observed in the palladium catalyzed allylation of "soft" nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. © 1989.

U2 - 10.1016/S0040-4039(00)99415-2

DO - 10.1016/S0040-4039(00)99415-2

M3 - Article

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SP - 3109

EP - 3112

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