Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

Marcial Moreno-Mañas; Jordi Ribas

doi:10.1016/S0040-4039(00)99415-2

Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

Marcial Moreno-Mañas, Jordi Ribas

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

17 Citations (Scopus)

Abstract

A high regioselectivity has been observed in the palladium catalyzed allylation of "soft" nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. © 1989.

Original language	English
Pages (from-to)	3109-3112
Journal	Tetrahedron Letters
Volume	30
Issue number	23
DOIs	https://doi.org/10.1016/S0040-4039(00)99415-2
Publication status	Published - 1 Jan 1989

Access to Document

10.1016/S0040-4039(00)99415-2

Cite this

@article{56b943ec65ce497d9bd948a173282f5a,

title = "Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes",

abstract = "A high regioselectivity has been observed in the palladium catalyzed allylation of {"}soft{"} nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. {\textcopyright} 1989.",

author = "Marcial Moreno-Ma{\~n}as and Jordi Ribas",

year = "1989",

month = jan,

day = "1",

doi = "10.1016/S0040-4039(00)99415-2",

language = "English",

volume = "30",

pages = "3109--3112",

number = "23",

}

TY - JOUR

T1 - Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

AU - Moreno-Mañas, Marcial

AU - Ribas, Jordi

PY - 1989/1/1

Y1 - 1989/1/1

N2 - A high regioselectivity has been observed in the palladium catalyzed allylation of "soft" nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. © 1989.

AB - A high regioselectivity has been observed in the palladium catalyzed allylation of "soft" nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. © 1989.

U2 - 10.1016/S0040-4039(00)99415-2

DO - 10.1016/S0040-4039(00)99415-2

M3 - Article

VL - 30

SP - 3109

EP - 3112

IS - 23

ER -

Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

Abstract

Access to Document

Fingerprint

Cite this