Electronic effects in the regioselectivity of nucleophilic attacks on cationic 1,3-diaryl-π-allylpalladium complexes

Maria Prat; Jordi Ribas; Marcial Moreno-Mañas

doi:10.1016/S0040-4020(01)88728-7

Electronic effects in the regioselectivity of nucleophilic attacks on cationic 1,3-diaryl-π-allylpalladium complexes

Maria Prat, Jordi Ribas, Marcial Moreno-Mañas

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

35 Citations (Scopus)

Abstract

Nucleophilic attacks on π-allylpalladium complexes derived from O2NPh(CHCHCH)PhX systems (X = 4-OMe and 4-Cl) occur prefentially at the allylic terminus remote from the electron-withdrawing group (NO2). © 1992.

Original language	English
Pages (from-to)	1695-1706
Journal	Tetrahedron
Volume	48
Issue number	9
DOIs	https://doi.org/10.1016/S0040-4020(01)88728-7
Publication status	Published - 28 Feb 1992

Keywords

allylation of nucleophiles
electronic effects
Palladium catalysis
regioselectivity

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title = "Electronic effects in the regioselectivity of nucleophilic attacks on cationic 1,3-diaryl-π-allylpalladium complexes",

abstract = "Nucleophilic attacks on π-allylpalladium complexes derived from O2NPh(CHCHCH)PhX systems (X = 4-OMe and 4-Cl) occur prefentially at the allylic terminus remote from the electron-withdrawing group (NO2). {\textcopyright} 1992.",

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T1 - Electronic effects in the regioselectivity of nucleophilic attacks on cationic 1,3-diaryl-π-allylpalladium complexes

AU - Prat, Maria

AU - Ribas, Jordi

AU - Moreno-Mañas, Marcial

PY - 1992/2/28

Y1 - 1992/2/28

N2 - Nucleophilic attacks on π-allylpalladium complexes derived from O2NPh(CHCHCH)PhX systems (X = 4-OMe and 4-Cl) occur prefentially at the allylic terminus remote from the electron-withdrawing group (NO2). © 1992.

AB - Nucleophilic attacks on π-allylpalladium complexes derived from O2NPh(CHCHCH)PhX systems (X = 4-OMe and 4-Cl) occur prefentially at the allylic terminus remote from the electron-withdrawing group (NO2). © 1992.

KW - allylation of nucleophiles

KW - electronic effects

KW - Palladium catalysis

KW - regioselectivity

U2 - 10.1016/S0040-4020(01)88728-7

DO - 10.1016/S0040-4020(01)88728-7

M3 - Article

VL - 48

SP - 1695

EP - 1706

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 9

ER -