Electronic effects in the regioselectivity of nucleophilic attacks on cationic 1,3-diaryl-π-allylpalladium complexes

Maria Prat, Jordi Ribas, Marcial Moreno-Mañas

Research output: Contribution to journalArticleResearchpeer-review

35 Citations (Scopus)

Abstract

Nucleophilic attacks on π-allylpalladium complexes derived from O2NPh(CHCHCH)PhX systems (X = 4-OMe and 4-Cl) occur prefentially at the allylic terminus remote from the electron-withdrawing group (NO2). © 1992.
Original languageEnglish
Pages (from-to)1695-1706
JournalTetrahedron
Volume48
Issue number9
DOIs
Publication statusPublished - 28 Feb 1992

Keywords

  • allylation of nucleophiles
  • electronic effects
  • Palladium catalysis
  • regioselectivity

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