Electron Bottleneck in the Charge/Discharge Mechanism of Lithium Titanates for Batteries

Edgar Ventosa, Marcel Skoumal, Francisco Javier Vazquez, Cristina Flox, Jordi Arbiol, Joan Ramon Morante

    Research output: Contribution to journalArticleResearchpeer-review

    14 Citations (Scopus)


    © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. The semi-solid flow battery (SSFB) is a promising storage energy technology featured by employing semi-solid fluid electrodes containing conductive additive and active Li-ion battery materials. The state of art anode material for SSFB is Li4Ti5O12 (LTO). This work shows that LTO improves drastically the performance in fluid electrode via hydrogen annealing manifesting the importance of the electrical conductivity of the active material in SSFBs. On the other hand, the properties of fluid electrodes allow the contributions of ionic and electrical resistance to be separated in operando. The asymmetric overpotential observed in Li4Ti5O12 and TiO2 is proposed to originate from the so-called electron bottleneck mechanism based on the transformation from electrically insulator to conductor upon (de-)lithiation, or vice versa, which should be considered when modelling, evaluating or designing advanced materials based on Li4Ti5O12, TiO2 or others with insulating-conducting behavior materials.
    Original languageEnglish
    Pages (from-to)1737-1744
    Issue number10
    Publication statusPublished - 11 May 2015


    • batteries
    • conductivity
    • metal oxides
    • oxidation
    • reduction


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