Electrochemical synthesis of alkyl nitroaromatic compounds

Iluminada Gallardo; Gonzalo Guirado; Jordi Marquet

doi:10.1021/jo025898k

Electrochemical synthesis of alkyl nitroaromatic compounds

Iluminada Gallardo, Gonzalo Guirado, Jordi Marquet

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

22 Citations (Scopus)

Abstract

Alkyl nitroaromatic compounds were readily prepared via nucleophilic aromatic substitution for hydrogen or a heteroatom by electrochemical oxidation of the a-complex. Butyllithium and butylmagnesium chloride were used as nucleophiles, and several nitrocompounds were tested to explore the possibilities of the NASH and NASX reactions promoted electrochemically.

Original language	English
Pages (from-to)	631-633
Journal	Journal of Organic Chemistry
Volume	68
Issue number	2
DOIs	https://doi.org/10.1021/jo025898k
Publication status	Published - 24 Jan 2003

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title = "Electrochemical synthesis of alkyl nitroaromatic compounds",

abstract = "Alkyl nitroaromatic compounds were readily prepared via nucleophilic aromatic substitution for hydrogen or a heteroatom by electrochemical oxidation of the a-complex. Butyllithium and butylmagnesium chloride were used as nucleophiles, and several nitrocompounds were tested to explore the possibilities of the NASH and NASX reactions promoted electrochemically.",

author = "Iluminada Gallardo and Gonzalo Guirado and Jordi Marquet",

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journal = "Journal of Organic Chemistry",

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T1 - Electrochemical synthesis of alkyl nitroaromatic compounds

AU - Gallardo, Iluminada

AU - Guirado, Gonzalo

AU - Marquet, Jordi

PY - 2003/1/24

Y1 - 2003/1/24

N2 - Alkyl nitroaromatic compounds were readily prepared via nucleophilic aromatic substitution for hydrogen or a heteroatom by electrochemical oxidation of the a-complex. Butyllithium and butylmagnesium chloride were used as nucleophiles, and several nitrocompounds were tested to explore the possibilities of the NASH and NASX reactions promoted electrochemically.

AB - Alkyl nitroaromatic compounds were readily prepared via nucleophilic aromatic substitution for hydrogen or a heteroatom by electrochemical oxidation of the a-complex. Butyllithium and butylmagnesium chloride were used as nucleophiles, and several nitrocompounds were tested to explore the possibilities of the NASH and NASX reactions promoted electrochemically.

U2 - 10.1021/jo025898k

DO - 10.1021/jo025898k

M3 - Article

VL - 68

SP - 631

EP - 633

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 2

ER -

Electrochemical synthesis of alkyl nitroaromatic compounds

Abstract

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