Efficient hydroxycarbonylation of aryl iodides using recoverable and reusable carbon aerogels doped with palladium nanoparticles as catalyst

Sandro Cacchi; Cosmin L. Cotet; Giancarlo Fabrizi; Giovanni Forte; Antonella Goggiamani; Laura Martín; Sandra Martínez; Elies Molins; Marcial Moreno-Mañas; Francesco Petrucci; Anna Roig; Adelina Vallribera

doi:10.1016/j.tet.2006.12.024

Efficient hydroxycarbonylation of aryl iodides using recoverable and reusable carbon aerogels doped with palladium nanoparticles as catalyst

Sandro Cacchi, Cosmin L. Cotet, Giancarlo Fabrizi, Giovanni Forte, Antonella Goggiamani, Laura Martín, Sandra Martínez, Elies Molins, Marcial Moreno-Mañas, Francesco Petrucci, Anna Roig, Adelina Vallribera

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

32 Citations (Scopus)

Abstract

Electron-rich and electron-poor aryl iodides are converted, in high to excellent yields, into the corresponding carboxylic acids through a hydroxycarboxylation reaction catalyzed by a recoverable and reusable phosphine free palladium-carbon aerogel catalyst using lithium formate and acetic anhydride as an internal condensed source of carbon monoxide. The catalyst system can be reused several times without any appreciable loss of activity. © 2006.

Original language	English
Pages (from-to)	2519-2523
Journal	Tetrahedron
Volume	63
Issue number	11
DOIs	https://doi.org/10.1016/j.tet.2006.12.024
Publication status	Published - 12 Mar 2007

Keywords

Aerogels
Carboxylic acids
Nanoparticles
Palladium
Recycle

Access to Document

10.1016/j.tet.2006.12.024

Cite this

Cacchi, S., Cotet, C. L., Fabrizi, G., Forte, G., Goggiamani, A., Martín, L., Martínez, S., Molins, E., Moreno-Mañas, M., Petrucci, F., Roig, A., & Vallribera, A. (2007). Efficient hydroxycarbonylation of aryl iodides using recoverable and reusable carbon aerogels doped with palladium nanoparticles as catalyst. Tetrahedron, 63(11), 2519-2523. https://doi.org/10.1016/j.tet.2006.12.024

@article{9b6a488b1d964161b0b241750a021754,

title = "Efficient hydroxycarbonylation of aryl iodides using recoverable and reusable carbon aerogels doped with palladium nanoparticles as catalyst",

abstract = "Electron-rich and electron-poor aryl iodides are converted, in high to excellent yields, into the corresponding carboxylic acids through a hydroxycarboxylation reaction catalyzed by a recoverable and reusable phosphine free palladium-carbon aerogel catalyst using lithium formate and acetic anhydride as an internal condensed source of carbon monoxide. The catalyst system can be reused several times without any appreciable loss of activity. {\textcopyright} 2006.",

keywords = "Aerogels, Carboxylic acids, Nanoparticles, Palladium, Recycle",

author = "Sandro Cacchi and Cotet, {Cosmin L.} and Giancarlo Fabrizi and Giovanni Forte and Antonella Goggiamani and Laura Mart{\'i}n and Sandra Mart{\'i}nez and Elies Molins and Marcial Moreno-Ma{\~n}as and Francesco Petrucci and Anna Roig and Adelina Vallribera",

year = "2007",

month = mar,

day = "12",

doi = "10.1016/j.tet.2006.12.024",

language = "English",

volume = "63",

pages = "2519--2523",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "11",

}

Cacchi, S, Cotet, CL, Fabrizi, G, Forte, G, Goggiamani, A, Martín, L, Martínez, S, Molins, E, Moreno-Mañas, M, Petrucci, F, Roig, A & Vallribera, A 2007, 'Efficient hydroxycarbonylation of aryl iodides using recoverable and reusable carbon aerogels doped with palladium nanoparticles as catalyst', Tetrahedron, vol. 63, no. 11, pp. 2519-2523. https://doi.org/10.1016/j.tet.2006.12.024

TY - JOUR

T1 - Efficient hydroxycarbonylation of aryl iodides using recoverable and reusable carbon aerogels doped with palladium nanoparticles as catalyst

AU - Cacchi, Sandro

AU - Cotet, Cosmin L.

AU - Fabrizi, Giancarlo

AU - Forte, Giovanni

AU - Goggiamani, Antonella

AU - Martín, Laura

AU - Martínez, Sandra

AU - Molins, Elies

AU - Moreno-Mañas, Marcial

AU - Petrucci, Francesco

AU - Roig, Anna

AU - Vallribera, Adelina

PY - 2007/3/12

Y1 - 2007/3/12

N2 - Electron-rich and electron-poor aryl iodides are converted, in high to excellent yields, into the corresponding carboxylic acids through a hydroxycarboxylation reaction catalyzed by a recoverable and reusable phosphine free palladium-carbon aerogel catalyst using lithium formate and acetic anhydride as an internal condensed source of carbon monoxide. The catalyst system can be reused several times without any appreciable loss of activity. © 2006.

AB - Electron-rich and electron-poor aryl iodides are converted, in high to excellent yields, into the corresponding carboxylic acids through a hydroxycarboxylation reaction catalyzed by a recoverable and reusable phosphine free palladium-carbon aerogel catalyst using lithium formate and acetic anhydride as an internal condensed source of carbon monoxide. The catalyst system can be reused several times without any appreciable loss of activity. © 2006.

KW - Aerogels

KW - Carboxylic acids

KW - Nanoparticles

KW - Palladium

KW - Recycle

U2 - 10.1016/j.tet.2006.12.024

DO - 10.1016/j.tet.2006.12.024

M3 - Article

SN - 0040-4020

VL - 63

SP - 2519

EP - 2523

JO - Tetrahedron

JF - Tetrahedron

IS - 11

ER -

Efficient hydroxycarbonylation of aryl iodides using recoverable and reusable carbon aerogels doped with palladium nanoparticles as catalyst

Abstract

Keywords

Access to Document

Fingerprint

Cite this