Efficient hydroxycarbonylation of aryl iodides using recoverable and reusable carbon aerogels doped with palladium nanoparticles as catalyst

Sandro Cacchi, Cosmin L. Cotet, Giancarlo Fabrizi, Giovanni Forte, Antonella Goggiamani, Laura Martín, Sandra Martínez, Elies Molins, Marcial Moreno-Mañas, Francesco Petrucci, Anna Roig, Adelina Vallribera

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31 Citations (Scopus)

Abstract

Electron-rich and electron-poor aryl iodides are converted, in high to excellent yields, into the corresponding carboxylic acids through a hydroxycarboxylation reaction catalyzed by a recoverable and reusable phosphine free palladium-carbon aerogel catalyst using lithium formate and acetic anhydride as an internal condensed source of carbon monoxide. The catalyst system can be reused several times without any appreciable loss of activity. © 2006.
Original languageEnglish
Pages (from-to)2519-2523
JournalTetrahedron
Volume63
Issue number11
DOIs
Publication statusPublished - 12 Mar 2007

Keywords

  • Aerogels
  • Carboxylic acids
  • Nanoparticles
  • Palladium
  • Recycle

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    Cacchi, S., Cotet, C. L., Fabrizi, G., Forte, G., Goggiamani, A., Martín, L., Martínez, S., Molins, E., Moreno-Mañas, M., Petrucci, F., Roig, A., & Vallribera, A. (2007). Efficient hydroxycarbonylation of aryl iodides using recoverable and reusable carbon aerogels doped with palladium nanoparticles as catalyst. Tetrahedron, 63(11), 2519-2523. https://doi.org/10.1016/j.tet.2006.12.024