Dipole moments can be used to determine the conformation of calix[4]arenes

Javier de Mendoza, Pilar Prados, Nuria Campillo, Pedro M. Nieto, Concha Sáchez, Jean‐Pierre ‐P Fayet, Marie Claire Vertut, Carlos Jaime, José Elguero

Research output: Contribution to journalArticleResearchpeer-review

16 Citations (Scopus)

Abstract

Experimental dipole moments for nine calix[4]arenes of known conformation are reported. An additive model, based on MNDO calculations, has been used to discuss these values, as well as three reported other dipole moments. It appears that a combination of calculated dipole moments of the aromatic fragments and experimental values can be used to determine the preferred conformation of calix[4]arenes in solution. Copyright © 1993 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
Original languageEnglish
Pages (from-to)367-369
JournalRecueil des Travaux Chimiques des Pays‐Bas
Volume112
Issue number6
DOIs
Publication statusPublished - 1 Jan 1993

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