TY - JOUR
T1 - Dipole moments can be used to determine the conformation of calix[4]arenes
AU - de Mendoza, Javier
AU - Prados, Pilar
AU - Campillo, Nuria
AU - Nieto, Pedro M.
AU - Sáchez, Concha
AU - Fayet, Jean‐Pierre ‐P
AU - Vertut, Marie Claire
AU - Jaime, Carlos
AU - Elguero, José
PY - 1993/1/1
Y1 - 1993/1/1
N2 - Experimental dipole moments for nine calix[4]arenes of known conformation are reported. An additive model, based on MNDO calculations, has been used to discuss these values, as well as three reported other dipole moments. It appears that a combination of calculated dipole moments of the aromatic fragments and experimental values can be used to determine the preferred conformation of calix[4]arenes in solution. Copyright © 1993 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
AB - Experimental dipole moments for nine calix[4]arenes of known conformation are reported. An additive model, based on MNDO calculations, has been used to discuss these values, as well as three reported other dipole moments. It appears that a combination of calculated dipole moments of the aromatic fragments and experimental values can be used to determine the preferred conformation of calix[4]arenes in solution. Copyright © 1993 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
U2 - 10.1002/recl.19931120610
DO - 10.1002/recl.19931120610
M3 - Article
VL - 112
SP - 367
EP - 369
IS - 6
ER -