Diode array detectors in flow injection analysis. Simultaneous determination of rare earth metals with Arsenazo III

M. Blanco, J. Coello, J. Gené, H. Iturriaga, S. Maspoch

Research output: Contribution to journalArticleResearchpeer-review

12 Citations (Scopus)

Abstract

A flow injection spectrophotometric procedure for the simultaneous determination of rare earths with Arsenazo III is reported. The spectrum of the sample is recorded by using a diode array detector and the mixed spectra are resolved with the aid of a multicomponent analysis program based on a least-squares fitting algorithm. Binary mixtures of tervalent cations at concentrations between 0.5 and 2.5 μg/g and uranyl in the range 1.4-4.3 μg/g were accurately resolved by univariate calibration. The presence of thorium (2.8-7.0 μ/g) required the use of multivariate calibration in order to obtain accurate results. Tervalent cations were globally determined as lanthanum. The sampling rate was about 60 samples/h. The results obtained in the analysis of U and Th in a pitchblende agree well with the certified values. © 1990 Springer-Verlag.
Original languageEnglish
Pages (from-to)831-835
JournalFresenius Journal of Analytical Chemistry
Volume338
Issue number7
DOIs
Publication statusPublished - 1 Jan 1990

Fingerprint

Dive into the research topics of 'Diode array detectors in flow injection analysis. Simultaneous determination of rare earth metals with Arsenazo III'. Together they form a unique fingerprint.

Cite this