Dimethylthallium(III) Complexes with S, N and S, O Ligands: The Molecular Structure of Me<inf>2</inf>TIL (L = 1-Oxidopyridinium-2-thiolato)

María V. Castaño; Agustin Sanchez; Jose S. Casas; Jose Sordo; Jose L. Brianso; Juan F. Piniella; Xabier Solans; Gabriel Germain; Tony Debaerdemaeker; Julius Glaser

doi:10.1021/om00099a001

Dimethylthallium(III) Complexes with S, N and S, O Ligands: The Molecular Structure of Me<inf>2</inf>TIL (L = 1-Oxidopyridinium-2-thiolato)

María V. Castaño, Agustin Sanchez, Jose S. Casas, Jose Sordo, Jose L. Brianso, Juan F. Piniella, Xabier Solans, Gabriel Germain, Tony Debaerdemaeker, Julius Glaser

Department of Geology

Research output: Contribution to journal › Article › Research › peer-review

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Abstract

The reaction of heterocyclic thiolic derivatives HLnwith dimethylthallium(III) hydroxide yields Me2TlL compounds. The structure of dimethyl(1-oxidopyridinium-2-thiolato)thallium(III), Me2TlL5T, has been determined by X-ray analysis. Me2TlL5 crystals are monoclinic, space group P21/c, with a = 9.812 (3) Å, b = 7.616 (1) Å, c = 12.851 (3) Å, β = 97.48 (3) °, and Z = 4. The structure was refined to R = 0.016 for 929 unique data. In this compound the thallium atom is six-coordinate, if weak bridging interactions are considered, in lattices with polymeric chains. Spectroscopic data for the complexes OH, 13C, and 205T1 NMR, IR, and Raman) are discussed in order to determine possible structural/spectroscopic correlations. © 1988, American Chemical Society. All rights reserved.

Original language	English
Pages (from-to)	1897-1904
Journal	Organometallics
Volume	7
Issue number	9
DOIs	https://doi.org/10.1021/om00099a001
Publication status	Published - 1 Jan 1988

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@article{9a54f45959cd4f709e38ebe52989e8b1,

title = "Dimethylthallium(III) Complexes with S, N and S, O Ligands: The Molecular Structure of Me2TIL (L = 1-Oxidopyridinium-2-thiolato)",

abstract = "The reaction of heterocyclic thiolic derivatives HLnwith dimethylthallium(III) hydroxide yields Me2TlL compounds. The structure of dimethyl(1-oxidopyridinium-2-thiolato)thallium(III), Me2TlL5T, has been determined by X-ray analysis. Me2TlL5 crystals are monoclinic, space group P21/c, with a = 9.812 (3) {\AA}, b = 7.616 (1) {\AA}, c = 12.851 (3) {\AA}, β = 97.48 (3) °, and Z = 4. The structure was refined to R = 0.016 for 929 unique data. In this compound the thallium atom is six-coordinate, if weak bridging interactions are considered, in lattices with polymeric chains. Spectroscopic data for the complexes OH, 13C, and 205T1 NMR, IR, and Raman) are discussed in order to determine possible structural/spectroscopic correlations. {\textcopyright} 1988, American Chemical Society. All rights reserved.",

author = "Casta{\~n}o, {Mar{\'i}a V.} and Agustin Sanchez and Casas, {Jose S.} and Jose Sordo and Brianso, {Jose L.} and Piniella, {Juan F.} and Xabier Solans and Gabriel Germain and Tony Debaerdemaeker and Julius Glaser",

year = "1988",

month = jan,

day = "1",

doi = "10.1021/om00099a001",

language = "English",

volume = "7",

pages = "1897--1904",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Dimethylthallium(III) Complexes with S, N and S, O Ligands: The Molecular Structure of Me2TIL (L = 1-Oxidopyridinium-2-thiolato)

AU - Castaño, María V.

AU - Sanchez, Agustin

AU - Casas, Jose S.

AU - Sordo, Jose

AU - Brianso, Jose L.

AU - Piniella, Juan F.

AU - Solans, Xabier

AU - Germain, Gabriel

AU - Debaerdemaeker, Tony

AU - Glaser, Julius

PY - 1988/1/1

Y1 - 1988/1/1

N2 - The reaction of heterocyclic thiolic derivatives HLnwith dimethylthallium(III) hydroxide yields Me2TlL compounds. The structure of dimethyl(1-oxidopyridinium-2-thiolato)thallium(III), Me2TlL5T, has been determined by X-ray analysis. Me2TlL5 crystals are monoclinic, space group P21/c, with a = 9.812 (3) Å, b = 7.616 (1) Å, c = 12.851 (3) Å, β = 97.48 (3) °, and Z = 4. The structure was refined to R = 0.016 for 929 unique data. In this compound the thallium atom is six-coordinate, if weak bridging interactions are considered, in lattices with polymeric chains. Spectroscopic data for the complexes OH, 13C, and 205T1 NMR, IR, and Raman) are discussed in order to determine possible structural/spectroscopic correlations. © 1988, American Chemical Society. All rights reserved.

AB - The reaction of heterocyclic thiolic derivatives HLnwith dimethylthallium(III) hydroxide yields Me2TlL compounds. The structure of dimethyl(1-oxidopyridinium-2-thiolato)thallium(III), Me2TlL5T, has been determined by X-ray analysis. Me2TlL5 crystals are monoclinic, space group P21/c, with a = 9.812 (3) Å, b = 7.616 (1) Å, c = 12.851 (3) Å, β = 97.48 (3) °, and Z = 4. The structure was refined to R = 0.016 for 929 unique data. In this compound the thallium atom is six-coordinate, if weak bridging interactions are considered, in lattices with polymeric chains. Spectroscopic data for the complexes OH, 13C, and 205T1 NMR, IR, and Raman) are discussed in order to determine possible structural/spectroscopic correlations. © 1988, American Chemical Society. All rights reserved.

U2 - 10.1021/om00099a001

DO - 10.1021/om00099a001

M3 - Article

SN - 0276-7333

VL - 7

SP - 1897

EP - 1904

JO - Organometallics

JF - Organometallics

IS - 9

ER -

Dimethylthallium(III) Complexes with S, N and S, O Ligands: The Molecular Structure of Me<inf>2</inf>TIL (L = 1-Oxidopyridinium-2-thiolato)

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