Dihydrogen complexes: Striking effect of ion pairing to BF<inf>4</inf>- on the rotation of coordinated dihydrogen and the 19F relaxation time

Andrés G. Algarra; María J. Fernández-Trujillo; Agustí Lledós; Manuel G. Basallote

doi:10.1039/b906330g

Dihydrogen complexes: Striking effect of ion pairing to BF<inf>4</inf>- on the rotation of coordinated dihydrogen and the 19F relaxation time

Andrés G. Algarra, María J. Fernández-Trujillo, Agustí Lledós, Manuel G. Basallote

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

7 Citations (Scopus)

Abstract

Unexpected changes in the T1 values for the 19F NMR signal of the BF4- anion in the presence of dihydrogen complexes reveal that ion pairing with BF4-⋯H 2 interactions of different strengths can lead to significant changes in the rotation barrier for coordinated dihydrogen. © The Royal Society of Chemistry 2009.

Original language	English
Pages (from-to)	4563-4565
Journal	Chemical Communications
Issue number	30
DOIs	https://doi.org/10.1039/b906330g
Publication status	Published - 10 Aug 2009

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10.1039/b906330g

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title = "Dihydrogen complexes: Striking effect of ion pairing to BF4- on the rotation of coordinated dihydrogen and the 19F relaxation time",

abstract = "Unexpected changes in the T1 values for the 19F NMR signal of the BF4- anion in the presence of dihydrogen complexes reveal that ion pairing with BF4-⋯H 2 interactions of different strengths can lead to significant changes in the rotation barrier for coordinated dihydrogen. {\textcopyright} The Royal Society of Chemistry 2009.",

author = "Algarra, {Andr{\'e}s G.} and Fern{\'a}ndez-Trujillo, {Mar{\'i}a J.} and Agust{\'i} Lled{\'o}s and Basallote, {Manuel G.}",

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doi = "10.1039/b906330g",

language = "English",

pages = "4563--4565",

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Dihydrogen complexes: Striking effect of ion pairing to BF<inf>4</inf>- on the rotation of coordinated dihydrogen and the 19F relaxation time. / Algarra, Andrés G.; Fernández-Trujillo, María J.; Lledós, Agustí et al.

In: Chemical Communications, No. 30, 10.08.2009, p. 4563-4565.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Dihydrogen complexes: Striking effect of ion pairing to BF4- on the rotation of coordinated dihydrogen and the 19F relaxation time

AU - Algarra, Andrés G.

AU - Fernández-Trujillo, María J.

AU - Lledós, Agustí

AU - Basallote, Manuel G.

PY - 2009/8/10

Y1 - 2009/8/10

N2 - Unexpected changes in the T1 values for the 19F NMR signal of the BF4- anion in the presence of dihydrogen complexes reveal that ion pairing with BF4-⋯H 2 interactions of different strengths can lead to significant changes in the rotation barrier for coordinated dihydrogen. © The Royal Society of Chemistry 2009.

AB - Unexpected changes in the T1 values for the 19F NMR signal of the BF4- anion in the presence of dihydrogen complexes reveal that ion pairing with BF4-⋯H 2 interactions of different strengths can lead to significant changes in the rotation barrier for coordinated dihydrogen. © The Royal Society of Chemistry 2009.

U2 - 10.1039/b906330g

DO - 10.1039/b906330g

M3 - Article

SP - 4563

EP - 4565

IS - 30

ER -

Dihydrogen complexes: Striking effect of ion pairing to BF<inf>4</inf><sup>-</sup> on the rotation of coordinated dihydrogen and the <sup>19</sup>F relaxation time

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