Dihydrogen complexes: Striking effect of ion pairing to BF<inf>4</inf><sup>-</sup> on the rotation of coordinated dihydrogen and the <sup>19</sup>F relaxation time

Andrés G. Algarra, María J. Fernández-Trujillo, Agustí Lledós, Manuel G. Basallote

Research output: Contribution to journalArticleResearchpeer-review

7 Citations (Scopus)

Abstract

Unexpected changes in the T1 values for the 19F NMR signal of the BF4- anion in the presence of dihydrogen complexes reveal that ion pairing with BF4-⋯H 2 interactions of different strengths can lead to significant changes in the rotation barrier for coordinated dihydrogen. © The Royal Society of Chemistry 2009.
Original languageEnglish
Pages (from-to)4563-4565
JournalChemical Communications
Issue number30
DOIs
Publication statusPublished - 10 Aug 2009

Fingerprint Dive into the research topics of 'Dihydrogen complexes: Striking effect of ion pairing to BF<inf>4</inf><sup>-</sup> on the rotation of coordinated dihydrogen and the <sup>19</sup>F relaxation time'. Together they form a unique fingerprint.

  • Cite this