TY - JOUR
T1 - Diels-alder cycloadditions of chiral butenolides with cyclopentadiene: endo/exo selectivity
AU - Batllori, Rosa
AU - Font, Josep
AU - Monsalvatje, Montserrat
AU - Ortuño, Rosa M.
AU - Sanchez-Ferrando, Francisco
PY - 1989/1/1
Y1 - 1989/1/1
N2 - Chiral butenolides are revealed to be good dienophiles in Diels-Alder reactions with cyclopentadiene, affording endo and exo adducts, whose fully characterization is provided. Selectivity of these cycloaddition reactions has been shown to be temperature dependent not as a result of a thermodynamic equilibrium between the isomers, but due to a kinetically controlled process. © 1989.
AB - Chiral butenolides are revealed to be good dienophiles in Diels-Alder reactions with cyclopentadiene, affording endo and exo adducts, whose fully characterization is provided. Selectivity of these cycloaddition reactions has been shown to be temperature dependent not as a result of a thermodynamic equilibrium between the isomers, but due to a kinetically controlled process. © 1989.
U2 - 10.1016/S0040-4020(01)80048-X
DO - 10.1016/S0040-4020(01)80048-X
M3 - Article
VL - 45
SP - 1833
EP - 1838
JO - Tetrahedron
JF - Tetrahedron
SN - 0040-4020
IS - 6
ER -