Diels-alder cycloadditions of chiral butenolides with cyclopentadiene: endo/exo selectivity

Rosa Batllori; Josep Font; Montserrat Monsalvatje; Rosa M. Ortuño; Francisco Sanchez-Ferrando

doi:10.1016/S0040-4020(01)80048-X

Diels-alder cycloadditions of chiral butenolides with cyclopentadiene: endo/exo selectivity

Rosa Batllori, Josep Font, Montserrat Monsalvatje, Rosa M. Ortuño, Francisco Sanchez-Ferrando

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

29 Citations (Scopus)

Abstract

Chiral butenolides are revealed to be good dienophiles in Diels-Alder reactions with cyclopentadiene, affording endo and exo adducts, whose fully characterization is provided. Selectivity of these cycloaddition reactions has been shown to be temperature dependent not as a result of a thermodynamic equilibrium between the isomers, but due to a kinetically controlled process. © 1989.

Original language	English
Pages (from-to)	1833-1838
Journal	Tetrahedron
Volume	45
Issue number	6
DOIs	https://doi.org/10.1016/S0040-4020(01)80048-X
Publication status	Published - 1 Jan 1989

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title = "Diels-alder cycloadditions of chiral butenolides with cyclopentadiene: endo/exo selectivity",

abstract = "Chiral butenolides are revealed to be good dienophiles in Diels-Alder reactions with cyclopentadiene, affording endo and exo adducts, whose fully characterization is provided. Selectivity of these cycloaddition reactions has been shown to be temperature dependent not as a result of a thermodynamic equilibrium between the isomers, but due to a kinetically controlled process. {\textcopyright} 1989.",

author = "Rosa Batllori and Josep Font and Montserrat Monsalvatje and Ortu{\~n}o, {Rosa M.} and Francisco Sanchez-Ferrando",

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T1 - Diels-alder cycloadditions of chiral butenolides with cyclopentadiene: endo/exo selectivity

AU - Batllori, Rosa

AU - Font, Josep

AU - Monsalvatje, Montserrat

AU - Ortuño, Rosa M.

AU - Sanchez-Ferrando, Francisco

PY - 1989/1/1

Y1 - 1989/1/1

N2 - Chiral butenolides are revealed to be good dienophiles in Diels-Alder reactions with cyclopentadiene, affording endo and exo adducts, whose fully characterization is provided. Selectivity of these cycloaddition reactions has been shown to be temperature dependent not as a result of a thermodynamic equilibrium between the isomers, but due to a kinetically controlled process. © 1989.

AB - Chiral butenolides are revealed to be good dienophiles in Diels-Alder reactions with cyclopentadiene, affording endo and exo adducts, whose fully characterization is provided. Selectivity of these cycloaddition reactions has been shown to be temperature dependent not as a result of a thermodynamic equilibrium between the isomers, but due to a kinetically controlled process. © 1989.

U2 - 10.1016/S0040-4020(01)80048-X

DO - 10.1016/S0040-4020(01)80048-X

M3 - Article

VL - 45

SP - 1833

EP - 1838

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 6

ER -