Diastereoselective and highly efficient radical approach to (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol

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Abstract

The pure enantiomers (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol are prepared by a highly efficient radical deoxygenation under mild conditions of secondary hydroxyl groups. © 1994.
Original languageEnglish
Pages (from-to)2587-2588
JournalTetrahedron Letters
Volume35
Issue number16
DOIs
Publication statusPublished - 18 Apr 1994

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