Diastereoselective and highly efficient radical approach to (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol

Ramón Alibés; José L. Bourdelande; Josep Font

doi:10.1016/S0040-4039(00)77178-4

Diastereoselective and highly efficient radical approach to (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol

Ramón Alibés, José L. Bourdelande, Josep Font

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

9 Citations (Scopus)

Abstract

The pure enantiomers (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol are prepared by a highly efficient radical deoxygenation under mild conditions of secondary hydroxyl groups. © 1994.

Original language	English
Pages (from-to)	2587-2588
Journal	Tetrahedron Letters
Volume	35
Issue number	16
DOIs	https://doi.org/10.1016/S0040-4039(00)77178-4
Publication status	Published - 18 Apr 1994

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title = "Diastereoselective and highly efficient radical approach to (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol",

abstract = "The pure enantiomers (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol are prepared by a highly efficient radical deoxygenation under mild conditions of secondary hydroxyl groups. {\textcopyright} 1994.",

author = "Ram{\'o}n Alib{\'e}s and Bourdelande, {Jos{\'e} L.} and Josep Font",

year = "1994",

month = apr,

day = "18",

doi = "10.1016/S0040-4039(00)77178-4",

language = "English",

volume = "35",

pages = "2587--2588",

number = "16",

}

Diastereoselective and highly efficient radical approach to (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol. / Alibés, Ramón ; Bourdelande, José L.; Font, Josep.

In: Tetrahedron Letters, Vol. 35, No. 16, 18.04.1994, p. 2587-2588.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Diastereoselective and highly efficient radical approach to (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol

AU - Alibés, Ramón

AU - Bourdelande, José L.

AU - Font, Josep

PY - 1994/4/18

Y1 - 1994/4/18

N2 - The pure enantiomers (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol are prepared by a highly efficient radical deoxygenation under mild conditions of secondary hydroxyl groups. © 1994.

AB - The pure enantiomers (1S,6R) and (1R,6S)-2,2,6-trimethyl-3-oxabicyclo[4.2.0]octadecane, key intermediates in the synthesis of (+) and (-)-grandisol are prepared by a highly efficient radical deoxygenation under mild conditions of secondary hydroxyl groups. © 1994.

U2 - 10.1016/S0040-4039(00)77178-4

DO - 10.1016/S0040-4039(00)77178-4

M3 - Article

VL - 35

SP - 2587

EP - 2588

IS - 16

ER -