Diastereoselective alkylation of chiral derivatives of acetoacetic acid

Marcial Moreno-Mañas; Rosa M. Sebastian; Adelina Vallribera; Elies Molins

doi:10.1016/0040-4020(95)00643-M

Diastereoselective alkylation of chiral derivatives of acetoacetic acid

Marcial Moreno-Mañas, Rosa M. Sebastian, Adelina Vallribera, Elies Molins

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

14 Citations (Scopus)

Abstract

N-acetoacetyl-(S)-4-benzyloxazolidin-2-one and N-acctoacetyl-(R)-bornane-10,2-sultam are alkylated at the C-α of the acctoacetyl moiety with significant diastereoisomeric excesses. The diastereoisomers are in general easily separable and configurationally fairly stable. © 1995 Elsevier Science Ltd.

Original language	English
Pages (from-to)	10795-10800
Journal	Tetrahedron
Volume	51
Issue number	39
DOIs	https://doi.org/10.1016/0040-4020(95)00643-M
Publication status	Published - 25 Sept 1995

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title = "Diastereoselective alkylation of chiral derivatives of acetoacetic acid",

abstract = "N-acetoacetyl-(S)-4-benzyloxazolidin-2-one and N-acctoacetyl-(R)-bornane-10,2-sultam are alkylated at the C-α of the acctoacetyl moiety with significant diastereoisomeric excesses. The diastereoisomers are in general easily separable and configurationally fairly stable. {\textcopyright} 1995 Elsevier Science Ltd.",

author = "Marcial Moreno-Ma{\~n}as and Sebastian, {Rosa M.} and Adelina Vallribera and Elies Molins",

year = "1995",

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day = "25",

doi = "10.1016/0040-4020(95)00643-M",

language = "English",

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journal = "Tetrahedron",

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T1 - Diastereoselective alkylation of chiral derivatives of acetoacetic acid

AU - Moreno-Mañas, Marcial

AU - Sebastian, Rosa M.

AU - Vallribera, Adelina

AU - Molins, Elies

PY - 1995/9/25

Y1 - 1995/9/25

N2 - N-acetoacetyl-(S)-4-benzyloxazolidin-2-one and N-acctoacetyl-(R)-bornane-10,2-sultam are alkylated at the C-α of the acctoacetyl moiety with significant diastereoisomeric excesses. The diastereoisomers are in general easily separable and configurationally fairly stable. © 1995 Elsevier Science Ltd.

AB - N-acetoacetyl-(S)-4-benzyloxazolidin-2-one and N-acctoacetyl-(R)-bornane-10,2-sultam are alkylated at the C-α of the acctoacetyl moiety with significant diastereoisomeric excesses. The diastereoisomers are in general easily separable and configurationally fairly stable. © 1995 Elsevier Science Ltd.

U2 - 10.1016/0040-4020(95)00643-M

DO - 10.1016/0040-4020(95)00643-M

M3 - Article

SN - 0040-4020

VL - 51

SP - 10795

EP - 10800

JO - Tetrahedron

JF - Tetrahedron

IS - 39

ER -

Diastereoselective alkylation of chiral derivatives of acetoacetic acid

Abstract

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