TY - JOUR
T1 - Desulfinylation of Ag(I) Sulfinyl Mesoionic Carbenes: Preparation of C-Unsubstituted Au(I)-1,2,3-Triazole Carbene Complexes
AU - Frutos, María
AU - Ortuño, Manuel A.
AU - Lledos, Agustí
AU - Viso, Alma
AU - Fernández De La Pradilla, Roberto
AU - De La Torre, María C.
AU - Sierra, Miguel A.
AU - Gornitzka, Heinz
AU - Hemmert, Catherine
PY - 2017/2/17
Y1 - 2017/2/17
N2 - © 2017 American Chemical Society. New and well-characterized Ag-bis(1,2,3-triazolylidene) complexes having enantiopure (S)-sulfoxides upon sequential treatment with alcohols and Au(I) form separable mixtures of regioisomeric C-unsubstituted Au-1,2,3-triazolylidene complexes. Mechanistic studies and DFT calculations support a desulfinylation process for in situ generated free triazolylidene salts.
AB - © 2017 American Chemical Society. New and well-characterized Ag-bis(1,2,3-triazolylidene) complexes having enantiopure (S)-sulfoxides upon sequential treatment with alcohols and Au(I) form separable mixtures of regioisomeric C-unsubstituted Au-1,2,3-triazolylidene complexes. Mechanistic studies and DFT calculations support a desulfinylation process for in situ generated free triazolylidene salts.
U2 - 10.1021/acs.orglett.6b03808
DO - 10.1021/acs.orglett.6b03808
M3 - Article
SN - 1523-7060
VL - 19
SP - 822
EP - 825
JO - Organic Letters
JF - Organic Letters
IS - 4
ER -