### Abstract

For general irreversible deposition processes, a relation between the variance σ2 of the number of deposited particles on subsystems out of a large surface and the available surface function Φ is obtained. This relation is based on a mean field assumption and follows the resolution of a master equation system. It is valid at low to intermediate values of the surface coverage θ as shown by comparison with exact results and with numerical simulations for special deposition models. In the low coverage limit, if the available surface function is written as a series expansion of the coverage θ, whose first nontrivial term varies as θk, the reduced variance has a similar expansion. However, the prefactor of θk derived in this article is in general different in both series expansions. This result has also been obtained by a rigorous argument based on the evolution of the k-particle distribution function with the coverage. © 1997 American Institute of Physics.

Original language | English |
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Pages (from-to) | 2089-2095 |

Journal | Journal of Chemical Physics |

Volume | 107 |

Issue number | 6 |

DOIs | |

Publication status | Published - 8 Aug 1997 |

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## Cite this

Bafaluy, J., Schaaf, P., Senger, B., Voegel, J. C., & Pagonabarraga, I. (1997). Density fluctuations of assemblies of irreversibly deposited particles on solid surfaces.

*Journal of Chemical Physics*,*107*(6), 2089-2095. https://doi.org/10.1063/1.474559