Crystal structure and magnetic measurements of [Cr(en)<inf>3</inf>] [ZnCl<inf>4</inf>]Cl

J. Pons; J. Casabó; F. Palacio; M. C. Morón; X. Solans; Richard L. Carlin

doi:10.1016/S0020-1693(00)80603-9

Crystal structure and magnetic measurements of [Cr(en)<inf>3</inf>] [ZnCl<inf>4</inf>]Cl

J. Pons, J. Casabó, F. Palacio, M. C. Morón, X. Solans, Richard L. Carlin

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

8 Citations (Scopus)

Abstract

The compound [Cr(en)3][ZnCl4]Cl has been synthesized by reaction of CrCl3·6H2O, Zn and [Cr(en)3]2(SO4)3 in HCl. Its molecular and crystalline structure was determined by X-ray diffraction methods, being monoclinic, P21/c, a=21.215(3), b=12.532(2), c=13.707(2) Å, β=95.21°, V= 3629(2) Å3, Dx=1.738g cm-3, MW=474.9, Z= 8, F(000)=1928, λ(Mo Kα)=0.71069 Å, μ(Mo Kα)= 27.04 cm-1, 288 K. No significant exchange interactions between Cr(III) cations in the crystalline lattice were found. Curie-Weiss behavior was found in the three directions tested (g1=2.06±0.02,g2= 2.08±0.02,g3=2.09±0.01), T=1.2-1.4 K. © 1988.

Original language	English
Pages (from-to)	161-165
Journal	Inorganica Chimica Acta
Volume	146
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(00)80603-9
Publication status	Published - 15 Jun 1988

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Pons, J., Casabó, J., Palacio, F., Morón, M. C., Solans, X., & Carlin, R. L. (1988). Crystal structure and magnetic measurements of [Cr(en)<inf>3</inf>] [ZnCl<inf>4</inf>]Cl. Inorganica Chimica Acta, 146(2), 161-165. https://doi.org/10.1016/S0020-1693(00)80603-9

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title = "Crystal structure and magnetic measurements of [Cr(en)3] [ZnCl4]Cl",

abstract = "The compound [Cr(en)3][ZnCl4]Cl has been synthesized by reaction of CrCl3·6H2O, Zn and [Cr(en)3]2(SO4)3 in HCl. Its molecular and crystalline structure was determined by X-ray diffraction methods, being monoclinic, P21/c, a=21.215(3), b=12.532(2), c=13.707(2) {\AA}, β=95.21°, V= 3629(2) {\AA}3, Dx=1.738g cm-3, MW=474.9, Z= 8, F(000)=1928, λ(Mo Kα)=0.71069 {\AA}, μ(Mo Kα)= 27.04 cm-1, 288 K. No significant exchange interactions between Cr(III) cations in the crystalline lattice were found. Curie-Weiss behavior was found in the three directions tested (g1=2.06±0.02,g2= 2.08±0.02,g3=2.09±0.01), T=1.2-1.4 K. {\textcopyright} 1988.",

author = "J. Pons and J. Casab{\'o} and F. Palacio and Mor{\'o}n, {M. C.} and X. Solans and Carlin, {Richard L.}",

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T1 - Crystal structure and magnetic measurements of [Cr(en)3] [ZnCl4]Cl

AU - Pons, J.

AU - Casabó, J.

AU - Palacio, F.

AU - Morón, M. C.

AU - Solans, X.

AU - Carlin, Richard L.

PY - 1988/6/15

Y1 - 1988/6/15

N2 - The compound [Cr(en)3][ZnCl4]Cl has been synthesized by reaction of CrCl3·6H2O, Zn and [Cr(en)3]2(SO4)3 in HCl. Its molecular and crystalline structure was determined by X-ray diffraction methods, being monoclinic, P21/c, a=21.215(3), b=12.532(2), c=13.707(2) Å, β=95.21°, V= 3629(2) Å3, Dx=1.738g cm-3, MW=474.9, Z= 8, F(000)=1928, λ(Mo Kα)=0.71069 Å, μ(Mo Kα)= 27.04 cm-1, 288 K. No significant exchange interactions between Cr(III) cations in the crystalline lattice were found. Curie-Weiss behavior was found in the three directions tested (g1=2.06±0.02,g2= 2.08±0.02,g3=2.09±0.01), T=1.2-1.4 K. © 1988.

AB - The compound [Cr(en)3][ZnCl4]Cl has been synthesized by reaction of CrCl3·6H2O, Zn and [Cr(en)3]2(SO4)3 in HCl. Its molecular and crystalline structure was determined by X-ray diffraction methods, being monoclinic, P21/c, a=21.215(3), b=12.532(2), c=13.707(2) Å, β=95.21°, V= 3629(2) Å3, Dx=1.738g cm-3, MW=474.9, Z= 8, F(000)=1928, λ(Mo Kα)=0.71069 Å, μ(Mo Kα)= 27.04 cm-1, 288 K. No significant exchange interactions between Cr(III) cations in the crystalline lattice were found. Curie-Weiss behavior was found in the three directions tested (g1=2.06±0.02,g2= 2.08±0.02,g3=2.09±0.01), T=1.2-1.4 K. © 1988.

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