TY - JOUR
T1 - Crystal and Molecular Structure of (BzlMe3N)2+[Fe2OCl6]2-
AU - Molins, Elies
AU - Roig, Anna
AU - Miravitlles, Carlos
AU - Moreno-Mañas, Marcial
AU - Vallribera, Adelina
AU - Gálvez, Nicanor
AU - Serra, Neus
PY - 1998/1/1
Y1 - 1998/1/1
N2 - The crystal and molecular structure of (BzlMe3N)2+[Fe2OCl6] 2- has been determined. The asymmetric unit contains two benzyltrimethylammonium cations and two half μ-oxo-bis(trichloroiron(III)) anions. The bridging μ-oxygen atoms of these anions are located over crystallographic symmetry elements. Therefore, the two anions resulting from the symmetry operations correspond to two different conformers presenting "angular" and "linear" dispositions of the Fe-O-Fe bond angle. Mössbauer spectrum consists of two asymmetric lines that are adequately simulated by two equally populated quadrupole doublets associated with the two iron sites.
AB - The crystal and molecular structure of (BzlMe3N)2+[Fe2OCl6] 2- has been determined. The asymmetric unit contains two benzyltrimethylammonium cations and two half μ-oxo-bis(trichloroiron(III)) anions. The bridging μ-oxygen atoms of these anions are located over crystallographic symmetry elements. Therefore, the two anions resulting from the symmetry operations correspond to two different conformers presenting "angular" and "linear" dispositions of the Fe-O-Fe bond angle. Mössbauer spectrum consists of two asymmetric lines that are adequately simulated by two equally populated quadrupole doublets associated with the two iron sites.
KW - Mössbauer spectroscopy
KW - X-ray diffraction
KW - μ-oxo-bis(trichloro-iron(III))
UR - https://www.scopus.com/pages/publications/0345824902
U2 - 10.1023/A:1022471014388
DO - 10.1023/A:1022471014388
M3 - Article
SN - 1040-0400
VL - 9
SP - 203
EP - 208
JO - Structural Chemistry
JF - Structural Chemistry
IS - 3
ER -