Correlating conduction properties with the molecular symmetry: Segregation of Z and e isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me <inf>2</inf> I <inf>2</inf> TTF] <inf>2</inf> Br

Olivier Jeannin, Enric Canadell, Pascale Auban-Senzier, Marc Fourmigué

    Research output: Contribution to journalArticleResearchpeer-review

    5 Citations (Scopus)

    Abstract

    © The Royal Society of Chemistry 2016. The Z and E isomers of the iodinated TTF derivative (Z,E)-Me 2 I 2 -TTF co-crystallize in a mixed-valence salt with Br - anions, and are segregated into Z and E stacks, each of them with a different charge localization pattern, which also revealed charge-assisted halogen bonding.
    Original languageEnglish
    Pages (from-to)308-311
    JournalChemical Communications
    Volume52
    Issue number2
    DOIs
    Publication statusPublished - 7 Jan 2016

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