Conversion of chemical scrubbers to biotrickling filters for VOCs and H <inf>2</inf> S treatment at low contact times

Alfredo Santos, Xavier Guimerà, Antonio David Dorado, Xavier Gamisans, David Gabriel

    Research output: Contribution to journalArticleResearchpeer-review

    16 Citations (Scopus)

    Abstract

    © 2014, Springer-Verlag Berlin Heidelberg. The purpose of this work was to evaluate the technical and economical feasibility of converting three chemical scrubbers in series to biotrickling filters (BTFs) for the simultaneous removal of H 2 S and volatile organic compounds (VOCs). The conversion of the full-scale scrubbers was based on previous conversion protocols. Conversion mainly required replacing the original carrier material and recycle pumps as well as modifying the controls and operation of the reactors. Complete removal of H 2 S and VOCs on a routine basis was reached at neutral pH in a longer period of time compared to previous conversions reported. Biotrickling filters operated at a gas contact time of about 1.4 s per reactor and at pH controlled between 6.5 and 6.8. Inlet average concentrations below 10 ppm v of H 2 S and below 5 ppm v for VOCs were often completely removed. The first and second bioreactors played a primary role in H 2 S removal. Year-round operation of the biotrickling filters proved the ability of the system to handle progressive load increases of H 2 S and VOCs. However, fast, sudden load changes often lead to reduced removal efficiencies. Odor analyses showed average removal efficiencies above 80 %. Gas chromatography-mass spectrometry of selected samples showed that outlet odor concentration was due to limited removal of VOCs. The conversion showed was economically viable taking into account the theoretical consumption of chemicals needed for the absorption and oxidation of both H 2 S and VOCs.
    Original languageEnglish
    Pages (from-to)67-76
    JournalApplied Microbiology and Biotechnology
    Volume99
    DOIs
    Publication statusPublished - 1 Jan 2015

    Keywords

    • Biotrickling filterm
    • Chemical scrubbers’ conversion
    • H S 2
    • Neutral pH operation
    • VOCs

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