Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

Rubén Sáez; Ciaran McArdle; Fouad Salhi; Jordi Marquet; Rosa M. Sebastián

doi:10.1039/c8sc04729d

Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

Rubén Sáez, Ciaran McArdle, Fouad Salhi, Jordi Marquet, Rosa M. Sebastián

Research output: Contribution to journal › Article › Research

14 Citations (Scopus)

Abstract

© The Royal Society of Chemistry. A hydrogenated frustrated Lewis pair ([TMPH+][HB(C6F5)3−]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.

Original language	English
Pages (from-to)	3295-3299
Number of pages	5
Journal	Chemical Science
Volume	10
Issue number	11
DOIs	https://doi.org/10.1039/c8sc04729d
Publication status	Published - 21 Mar 2019

Keywords

ADHESIVES
AMINES
COPOLYMERS
ETHYL CYANOACRYLATE
MONOMERS
NANOPARTICLES

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10.1039/c8sc04729d

https://ddd.uab.cat/record/215270

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title = "Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators",

abstract = "{\textcopyright} The Royal Society of Chemistry. A hydrogenated frustrated Lewis pair ([TMPH+][HB(C6F5)3−]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.",

keywords = "ADHESIVES, AMINES, COPOLYMERS, ETHYL CYANOACRYLATE, MONOMERS, NANOPARTICLES",

author = "Rub{\'e}n S{\'a}ez and Ciaran McArdle and Fouad Salhi and Jordi Marquet and Sebasti{\'a}n, {Rosa M.}",

year = "2019",

month = mar,

day = "21",

doi = "10.1039/c8sc04729d",

language = "English",

volume = "10",

pages = "3295--3299",

journal = "Chemical Science",

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TY - JOUR

T1 - Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

AU - Sáez, Rubén

AU - McArdle, Ciaran

AU - Salhi, Fouad

AU - Marquet, Jordi

AU - Sebastián, Rosa M.

PY - 2019/3/21

Y1 - 2019/3/21

N2 - © The Royal Society of Chemistry. A hydrogenated frustrated Lewis pair ([TMPH+][HB(C6F5)3−]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.

AB - © The Royal Society of Chemistry. A hydrogenated frustrated Lewis pair ([TMPH+][HB(C6F5)3−]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.

KW - ADHESIVES

KW - AMINES

KW - COPOLYMERS

KW - ETHYL CYANOACRYLATE

KW - MONOMERS

KW - NANOPARTICLES

UR - http://www.mendeley.com/research/controlled-living-anionic-polymerization-cyanoacrylates-frustrated-lewis-pair-based-initiators

U2 - 10.1039/c8sc04729d

DO - 10.1039/c8sc04729d

M3 - Article

C2 - 30996915

SN - 2041-6520

VL - 10

SP - 3295

EP - 3299

JO - Chemical Science

JF - Chemical Science

IS - 11

ER -

Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

Abstract

Keywords

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