Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

Rubén Sáez, Ciaran McArdle, Fouad Salhi, Jordi Marquet, Rosa M. Sebastián

Research output: Contribution to journalArticleResearch

3 Citations (Scopus)

Abstract

© The Royal Society of Chemistry. A hydrogenated frustrated Lewis pair ([TMPH+][HB(C6F5)3−]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.
Original languageEnglish
Pages (from-to)3295-3299
Number of pages5
JournalChemical Science
Volume10
Issue number11
DOIs
Publication statusPublished - 21 Mar 2019

Keywords

  • ADHESIVES
  • AMINES
  • COPOLYMERS
  • ETHYL CYANOACRYLATE
  • MONOMERS
  • NANOPARTICLES

Fingerprint Dive into the research topics of 'Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators'. Together they form a unique fingerprint.

Cite this