Conjugate addition to diethyl azodicarboxylate under organic- perfluorinated biphasic homogeneous catalysis by nickel(II) species

Miriam Meseguer; Marcial Moreno-Mañas; Adelina Vallribera

doi:10.1016/S0040-4039(00)00549-9

Conjugate addition to diethyl azodicarboxylate under organic- perfluorinated biphasic homogeneous catalysis by nickel(II) species

Miriam Meseguer, Marcial Moreno-Mañas, Adelina Vallribera

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

38 Citations (Scopus)

Abstract

The nickel(II) complex of the Schiff base of salicylaldehyde and 4- perfluorodecylaniline catalyzes the conjugate addition of β-diketones to electron-deficient substrates. Electrophilic amination with azodicarboxylate affords quaternary centers. The catalyst is recovered in solution and reutilized. Isolation of reaction products is very simple and does not require chromatography. (C) 2000 Elsevier Science Ltd.

Original language	English
Pages (from-to)	4093-4095
Journal	Tetrahedron Letters
Volume	41
Issue number	21
DOIs	https://doi.org/10.1016/S0040-4039(00)00549-9
Publication status	Published - 29 May 2000

Keywords

Amination
Catalysis
Michael reactions
Nickel(II)

Access to Document

10.1016/S0040-4039(00)00549-9

Cite this

@article{375d857f3a2b4026bc482d3329167a13,

title = "Conjugate addition to diethyl azodicarboxylate under organic- perfluorinated biphasic homogeneous catalysis by nickel(II) species",

abstract = "The nickel(II) complex of the Schiff base of salicylaldehyde and 4- perfluorodecylaniline catalyzes the conjugate addition of β-diketones to electron-deficient substrates. Electrophilic amination with azodicarboxylate affords quaternary centers. The catalyst is recovered in solution and reutilized. Isolation of reaction products is very simple and does not require chromatography. (C) 2000 Elsevier Science Ltd.",

keywords = "Amination, Catalysis, Michael reactions, Nickel(II)",

author = "Miriam Meseguer and Marcial Moreno-Ma{\~n}as and Adelina Vallribera",

year = "2000",

month = may,

day = "29",

doi = "10.1016/S0040-4039(00)00549-9",

language = "English",

volume = "41",

pages = "4093--4095",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "21",

}

TY - JOUR

T1 - Conjugate addition to diethyl azodicarboxylate under organic- perfluorinated biphasic homogeneous catalysis by nickel(II) species

AU - Meseguer, Miriam

AU - Moreno-Mañas, Marcial

AU - Vallribera, Adelina

PY - 2000/5/29

Y1 - 2000/5/29

N2 - The nickel(II) complex of the Schiff base of salicylaldehyde and 4- perfluorodecylaniline catalyzes the conjugate addition of β-diketones to electron-deficient substrates. Electrophilic amination with azodicarboxylate affords quaternary centers. The catalyst is recovered in solution and reutilized. Isolation of reaction products is very simple and does not require chromatography. (C) 2000 Elsevier Science Ltd.

AB - The nickel(II) complex of the Schiff base of salicylaldehyde and 4- perfluorodecylaniline catalyzes the conjugate addition of β-diketones to electron-deficient substrates. Electrophilic amination with azodicarboxylate affords quaternary centers. The catalyst is recovered in solution and reutilized. Isolation of reaction products is very simple and does not require chromatography. (C) 2000 Elsevier Science Ltd.

KW - Amination

KW - Catalysis

KW - Michael reactions

KW - Nickel(II)

U2 - 10.1016/S0040-4039(00)00549-9

DO - 10.1016/S0040-4039(00)00549-9

M3 - Article

SN - 0040-4039

VL - 41

SP - 4093

EP - 4095

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 21

ER -

Conjugate addition to diethyl azodicarboxylate under organic- perfluorinated biphasic homogeneous catalysis by nickel(II) species

Abstract

Keywords

Access to Document

Fingerprint

Cite this