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Communication : Growing room temperature ice with graphene

Albert Verdaguer Prats, Juan José Segura, Laura López-Mir, Guillaume Sauthier, Jordi Fraxedas

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    Abstract

    Water becomes ordered in the form of hexagonal ice at room temperature under controlled humidity conditions upon confinement in the nanometer range between protective graphene sheets and crystalline (111) surfaces with hexagonal symmetry of the alkali earth fluoride BaF₂. Interfacial water/substrate pseudoepitaxy turns out to be a critical parameter since ice is only formed when the lattice mismatch is small, an observation based on the absence of ice on (111) surfaces of isostructural CaF₂.
    Original languageEnglish
    JournalJournal of Chemical Physics
    Volume138
    Issue number12
    DOIs
    Publication statusPublished - 2013

    Keywords

    • Alkali-earth fluorides
    • Controlled humidities
    • Critical parameter
    • Graphene sheets
    • Hexagonal symmetry
    • Interfacial water
    • Nano meter range
    • Room temperature

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