Catalytic effect on the selectivity of the Diels-Alder reaction

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Abstract

Using the MINDO/3 method variation of the potential barrier for the Diels-Alder reaction between 1-hydroxybutadiene and acrolein, catalyzed by BF3 and NH4+, has been studied. An interpretation of the experimental facts about the increase regioselectivity, and stereoselectivity for Diels-Alder reactions catalyzed by Lewis acids is given. © 1983.
Original languageEnglish
Pages (from-to)378-380
JournalChemical Physics Letters
Volume97
Issue number4-5
DOIs
Publication statusPublished - 27 May 1983

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