Carbonylation of alkenyl-complexes of ruthenium. The formation of complexes containing, alkene or acyl ligands, and the reaction of the acyl complexes with methanol

M. Rosario Torres, Aurea Perales, Hassane Loumrhari, Josep Ros

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20 Citations (Scopus)

Abstract

The unsaturated complexes RuCl(CO)(RC=CHR′)(PPh3)2 react with CO to give the dicarbonyl complexes RuCl(CO)2(RC=CHR′)(PPh3)2 or the η2-acyl complexes RuCl(CO)(O=CC(R)=CHR′)(PPh3)2, depending on the R and R′ groups. The RuCl(CO)(O=CC(Me)=CHMe)(PPh3)2 complex reacts with methanol to give RuCl(CO)(O2CC(Me)=CHMe)(PPh3)2, which structure has been established by an X-ray diffraction study. © 1990.
Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume384
Issue number3
DOIs
Publication statusPublished - 6 Mar 1990

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