TY - JOUR
T1 - C-F bond activation in polyfluorobenzothiolate compounds of os(III)
AU - Arroyo, Maribel
AU - Bernès, Sylvain
AU - Brianso, Jose Luis
AU - Mayoral, Estela
AU - Richards, Raymond L.
AU - Rius, Jordi
AU - Torrens, Hugo
PY - 2000/4/15
Y1 - 2000/4/15
N2 - Thermolysis of [Os(SR)3(PMe2Ph)2] (R = C6F5 (1a) or C6HF4-4 (1b)) in refluxing toluene affords [Os(SC6F5)2-(o-S2C6F4)(PMe2Ph)] (2a), [Os(SC6HF4)2(o-S2C6HF3)(PMe2Ph)] (2b), and [Os(C6F5)2(o-S2C6F4)(PMe2Ph)2] (3a) through processes involving C-F and C-S bond cleavage as well as rearrangement of C-S bonds. The single-crystal diffraction structures of 1a, 2a and 3a have been determined. In the solid state compound 1a shows a C-F→Os interaction. © 2000 Elsevier Science S.A. All rights reserved.
AB - Thermolysis of [Os(SR)3(PMe2Ph)2] (R = C6F5 (1a) or C6HF4-4 (1b)) in refluxing toluene affords [Os(SC6F5)2-(o-S2C6F4)(PMe2Ph)] (2a), [Os(SC6HF4)2(o-S2C6HF3)(PMe2Ph)] (2b), and [Os(C6F5)2(o-S2C6F4)(PMe2Ph)2] (3a) through processes involving C-F and C-S bond cleavage as well as rearrangement of C-S bonds. The single-crystal diffraction structures of 1a, 2a and 3a have been determined. In the solid state compound 1a shows a C-F→Os interaction. © 2000 Elsevier Science S.A. All rights reserved.
KW - C-f bond activation
KW - Osmium
KW - Polyfluorobenzothiolate
KW - Thermolysis
UR - https://www.scopus.com/pages/publications/0034654742
U2 - 10.1016/S0022-328X(99)00760-3
DO - 10.1016/S0022-328X(99)00760-3
M3 - Article
SN - 0022-328X
VL - 599
SP - 170
EP - 177
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -