C-Allylation of L-Ascorbic Acid under Palladium(0) Catalysis

Marcial Moreno-Manas; Roser Pleixats; Mercè Villarroya

doi:10.1021/jo00303a032

C-Allylation of L-Ascorbic Acid under Palladium(0) Catalysis

Marcial Moreno-Manas, Roser Pleixats, Mercè Villarroya

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

24 Citations (Scopus)

Abstract

L-Ascorbic acid (1) is efficiently allylated at C-2 with primary and secondary allylic substrates by using palladium(0) catalysis. Hydrogenation of the resulting allylated compounds 6 affords L-ascorbic acid derivatives with saturated chains at C-2. © 1990, American Chemical Society. All rights reserved.

Original language	English
Pages (from-to)	4925-4928
Journal	Journal of Organic Chemistry
Volume	55
Issue number	16
DOIs	https://doi.org/10.1021/jo00303a032
Publication status	Published - 1 Jan 1990

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@article{231eef6cc5cc4edd81d39c80c63a4e1b,

title = "C-Allylation of L-Ascorbic Acid under Palladium(0) Catalysis",

abstract = "L-Ascorbic acid (1) is efficiently allylated at C-2 with primary and secondary allylic substrates by using palladium(0) catalysis. Hydrogenation of the resulting allylated compounds 6 affords L-ascorbic acid derivatives with saturated chains at C-2. {\textcopyright} 1990, American Chemical Society. All rights reserved.",

author = "Marcial Moreno-Manas and Roser Pleixats and Merc{\`e} Villarroya",

year = "1990",

month = jan,

day = "1",

doi = "10.1021/jo00303a032",

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volume = "55",

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journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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T1 - C-Allylation of L-Ascorbic Acid under Palladium(0) Catalysis

AU - Moreno-Manas, Marcial

AU - Pleixats, Roser

AU - Villarroya, Mercè

PY - 1990/1/1

Y1 - 1990/1/1

N2 - L-Ascorbic acid (1) is efficiently allylated at C-2 with primary and secondary allylic substrates by using palladium(0) catalysis. Hydrogenation of the resulting allylated compounds 6 affords L-ascorbic acid derivatives with saturated chains at C-2. © 1990, American Chemical Society. All rights reserved.

AB - L-Ascorbic acid (1) is efficiently allylated at C-2 with primary and secondary allylic substrates by using palladium(0) catalysis. Hydrogenation of the resulting allylated compounds 6 affords L-ascorbic acid derivatives with saturated chains at C-2. © 1990, American Chemical Society. All rights reserved.

U2 - 10.1021/jo00303a032

DO - 10.1021/jo00303a032

M3 - Article

SN - 0022-3263

VL - 55

SP - 4925

EP - 4928

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 16

ER -

C-Allylation of L-Ascorbic Acid under Palladium(0) Catalysis

Abstract

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