Bis[μ-4-(ethylammoniomethyl)-3, 5-dimethylpyrazolato-κ2N 1:N2] bis[(η41, 5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate

Glòria Esquius, Josefina Pons, Ramón Yáñez, Josep Ros, Xavier Solans, Mercè Font-Bardia

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13 Citations (Scopus)

Abstract

The molecular structure of the compound [Rh2(C8H15N3)2 (C8H12)2] Cl2·CH2Cl2·CH3OH was studied. The dinuclear Rh1 complex was found to have C2 symmetry with the two pyrazolato ligands acting as μ-bridges. The coordination of each Rh cation was completed by one cyclooctadiene (COD) ligand. The average Rh-C(COD) distance showed linear dependence on the Rh-N(pyrazole) distance due to steric hinderance produced by the packing.
Original languageEnglish
Pages (from-to)m133-m134
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume58
Issue number2
DOIs
Publication statusPublished - 1 Jan 2002

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