The molecular structure of the compound [Rh2(C8H15N3)2 (C8H12)2] Cl2·CH2Cl2·CH3OH was studied. The dinuclear Rh1 complex was found to have C2 symmetry with the two pyrazolato ligands acting as μ-bridges. The coordination of each Rh cation was completed by one cyclooctadiene (COD) ligand. The average Rh-C(COD) distance showed linear dependence on the Rh-N(pyrazole) distance due to steric hinderance produced by the packing.
|Journal||Acta Crystallographica Section C: Crystal Structure Communications|
|Publication status||Published - 1 Jan 2002|